A titanocene based metalloligand, Cp*2Ti(C22-py)2, was synthesized and coordinated to either Cu(I) or Pd(II). The metalloligand binds Cu(I) between its alkynes and Pd(II) between its pyridinyl rings, acting as a trans-bidentate ligand. In order to bind Pd(II), significant structural rearrangements were necessary, which required the flexibility of the C–Ti–C hinge on the titanocene metalloligand.
N. C. Vieira, J. A. Pienkos, C. D. McMillen, A. R. Myers, A. P. Clay and P. S. Wagenknecht, Dalton Trans., 2017, 46, 15195 DOI: 10.1039/C7DT03252H
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