Issue 39, 2013
From the journal:

Chemical Communications

Synthesis, structure and reactivity of cyclopropenyl-1-ylidene stabilized S(ii), Se(ii) and Te(ii) mono- and dications†‡

Ágnes Kozma,a   Jekaterina Petuškova,a   Christian W. Lehmanna  and  Manuel Alcarazo*a  

* Corresponding authors

a Max Planck Institut für Kohlenforschung, 45470-Mülheim an der Ruhr, Germany
E-mail: alcarazo@mpi-muelheim.mpg.de
Fax: +49 208 3062994
Tel: +49 208 3062428

Abstract

The syntheses and structural characterization of carbene-stabilized chalcogen centred mono- and dications employing a reverse electron demand onio-substitutent transfer strategy are reported. The electronic structures of these compounds were determined by density functional calculations and their reactivity towards Pd(0) centres was evaluated.

Graphical abstract: Synthesis, structure and reactivity of cyclopropenyl-1-ylidene stabilized S(ii), Se(ii) and Te(ii) mono- and dications

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/C2CC36225B
Article type
Communication
Submitted
27 Aug 2012
Accepted
12 Oct 2012
First published
29 Oct 2012

Chem. Commun., 2013,49, 4145-4147

Permissions

Request permissions

Synthesis, structure and reactivity of cyclopropenyl-1-ylidene stabilized S(II), Se(II) and Te(II) mono- and dications

Á. Kozma, J. Petuškova, C. W. Lehmann and M. Alcarazo, Chem. Commun., 2013, 49, 4145 DOI: 10.1039/C2CC36225B

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements