Porphyrin based porous organic polymers: novel synthetic strategy and exceptionally high CO2 adsorption capacity

Arindam Modak; Mahasweta Nandi; John Mondal; Asim Bhaumik

doi:10.1039/C1CC14275E

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Porphyrin based porous organic polymers: novel synthetic strategy and exceptionally high CO₂adsorption capacity†

Arindam Modak,^a Mahasweta Nandi,^a John Mondal^a and Asim Bhaumik*^a

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* Corresponding authors

^a Department of Materials Science, Indian Association for the Cultivation of Science, Jadavpur, Kolkata–700 032, India
E-mail: msab@iacs.res.in
Fax: +91-33-2473-2805
Tel: +91-33-2473-4971

Abstract

Iron containing porous organic polymers (Fe-POPs) have been synthesized by a facile one-pot bottom-up approach to porphyrin chemistry by an extended aromatic substitution reaction between pyrrole and aromatic dialdehydes in the presence of small amount of Fe(III). The Fe-POPs possess very high BET surface area, large micropores and showed excellent CO₂ capture (∼19 wt%) at 273 K/1 bar.

This article is part of the themed collection: ChemComm 60th Anniversary Historic Papers from India

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Article information

DOI: https://doi.org/10.1039/C1CC14275E
Article type: Communication
Submitted: 15 Quint 2011
Accepted: 24 Oct 2011
First published: 16 Nov 2011

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Chem. Commun., 2012,48, 248-250

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Porphyrin based porous organic polymers: novel synthetic strategy and exceptionally high CO₂ adsorption capacity

A. Modak, M. Nandi, J. Mondal and A. Bhaumik, Chem. Commun., 2012, 48, 248 DOI: 10.1039/C1CC14275E

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