Pulsed electrolysis: enhancing primary benzylic C(sp3)–H nucleophilic fluorination

Alexander P. Atkins, Atul K. Chaturvedi, Joseph A. Tate and Alastair J. J. Lennox

Org. Chem. Front., 2024, 11, 802
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Electrochemical remote C(sp3)–H thiocyanation

Xinyu Pang, Hui He, Xiangrui Meng, Linbao Zhang, Shaofei Ni, Ming Li and Weisi Guo

Org. Chem. Front., 2024, 11, 2283
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Divergent process for the catalytic decarboxylative thiocyanation and isothiocyanation of carboxylic acids promoted by visible light

Jordan Vigier, Mélissa Gao, Philippe Jubault, Hélène Lebel and Tatiana Besset

Chem. Commun., 2024, 60, 196
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Photoinduced benzylic C–H thiocyanation enabled by triphenylphosphine oxide and N-thiocyanophthalimide

Zhongmei Wang, Jiazhen Li, Xingyu Liu, Zhihe Zhang, Wen Gu, Zhengying You, Fan Luo and Shihui Liu

Chem. Commun., 2026, 62, 2615
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Bromine radical enhanced stoichiometric pyridylation of alkylarenes and diarylmethanes at room temperature

Qiao-Lin Wang, Huawen Huang, Guojiang Mao and Guo-Jun Deng

Org. Chem. Front., 2023, 10, 890
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Electrochemical cascade sequences for remote C7–H bond thiocyanation of quinoxalin-2(1H)-ones with ammonium thiocyanate

Rajib Maity, Abhijit Bankura and Indrajit Das

Green Chem., 2023, 25, 7774
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Photocatalytic C–H Thiocyanation of NH2-Enaminones and the Tunable Synthetic Routes to 2-Aminothiazoles and 2-Thiazolinones

Junlong Zeng, Jie-Ping Wan and Yunyun Liu

J. Org. Chem., 2022, 87, 13195
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Photoinduced Synthesis of Thiocyanates through Hydrogen Atom Transfer and One-Pot Derivatization to Isothiocyanates

Bumpei Maeda, Yusuke Aihara, Ayato Sato, Toshinori Kinoshita and Kei Murakami

Org. Lett., 2022, 24, 7366
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A Facile Electrochemical Strategy for the Azidation of Benzylic C(sp3)−H Bonds

Guoxue He, Yutian Li, Shengbin Zhou, Xiaohao Yang, Aolong Shang, Yunbo Wang, Hong Liu and Yu Zhou

Eur J Org Chem, 2022, 2022
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Electrophilic thiocyanation of aromatic, heteroaromatic and aliphatic compounds: A novel perspective on recent advances

Sobhan Rezayati, Maryam Manafi Moghadam, Ali Ramazani and Guoying Zhang

Tetrahedron, 2025, 179, 134645
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A General Strategy for C(sp3)─H Bond Etherification via Quinoline Derivative‐Mediated Electrolysis

Yousen Xu, Hao Wu, ChenXi Zhu, Minjun Tu and Lei Zhang

Advanced Science, 2025, 12
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Electrophotocatalytic Thiocyanation and Sulfonylation Cyclization of Unactivated Alkenes

Yingchun Ma, Ping Yu, Ruoyu Qin, Run He, Li Zeng, Lou Shi, Shaoguang Sun and Deqiang Liang

J. Org. Chem., 2025, 90, 598
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C‐Centered radical intermediates for C(sp3)‐H bonds functionalization: An emerging approach towards alkyl thiocyanates

Floris Buttard, Jordan Vigier, Hélène Lebel and Tatiana Besset

Eur J Org Chem, 2024, 27
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Electrochemical Desaturation and β-Thiocyanation of Cyclic Amides

Kaili Miao, Jin Zhang, Jiaxin Chen, Lin-Bao Zhang, Ming Li, Lirong Wen and Weisi Guo

Org. Lett., 2025, 27, 186
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Selective electrochemical thiocyanation/selenocyanation of C(sp3)-H and C(sp2)-H bonds

Zhihao Wang, Binbin Chen, Qing Pang, Jialei Xu, Jiabin Shen, Jun Xu and Wanmei Li

Molecular Catalysis, 2024, 559, 114060
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KI-Catalyzed Selective C(5)-Sulfenylation and C(5),C(7)-Disulfenylation of Unprotected 8-Aminoquinolines and the Indole C(2),C(3)-Disulfenylation

Wu Haozhi, Luo Tian, Jiang Jianwen and Wan Jieping

Chinese Journal of Organic Chemistry, 2022, 42, 3721
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Electrochemical Allylic C(sp3)–H Isothiocyanation via [3,3]-Sigmatropic Rearrangement

Xuezhuang Gao, Hui He, Kaili Miao, Linbao Zhang, Shao-Fei Ni, Ming Li and Weisi Guo

Org. Lett., 2024, 26, 4554
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Functional Reactions Facilitated by Carbon Electrodes

Xinyu Zhang, Ziyun Wang, Jiaxiu Liu, Lirong Wen, Ming Li, Weisi Guo and Lin-Bao Zhang

Synlett, 2025, 36, 1808
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Electrochemical Oxidative C–H Amination through a Ritter-Type Reaction

Yiwen Xu, Qiang Li, Runyou Ye, Buyi Xu and Xiangge Zhou

J. Org. Chem., 2023, 88, 9518
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Decatungstate Catalyzed Benzylic C−H Trifluoromethylthiolation

Meifang Tang, Yanyang Bao, Han Zhang, Rui Xiao, Bingbing Feng, Zheliang Yuan and Yanan Wang

Eur J Org Chem, 2024, 27
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TEMPO-Catalyzed Electrochemical Hydrobenzylation of Imines with Methylarenes via Radical Cascade Reaction

Kaifa Zhang, Kun Xia, Hui Chen, Yu Li, Ziwei Shan, Shuangming Zhang, Lei Zhou and Ablimit Abdukader

J. Org. Chem., 2025, 90, 14253
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Electrochemical radical-polar crossover: a radical approach to polar chemistry

Zhoumei Tan, Haonan Zhang, Kun Xu and Chengchu Zeng

Sci. China Chem., 2024, 67, 450
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Scalable and Selective Electrochemical Benzylic C–H Fluoroetherfication to Fluorinated Ethers

Yanyan Kong, Chao Wang, Xuemei Xu and Zekun Yang

Synthesis, 2026, 58, 562
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Recent Advances in Electrochemical Formation of C—S Bond and Construction of Organosulfur Compounds

Shiyi Zhuang, Xiaoqin You and Weiwei Jin

Chinese Journal of Organic Chemistry, 2025, 45, 3701
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Electrochemical Deoxygenation of Alcohols into Alkanes

Jiayi Liu, Xiao Li, Xinhao Chen, Tao Wang, Liantao Xin and Weisi Guo

Synthesis, 2023, 55, 2993
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Electrochemical Direct Formyloxylation of Benzylic C(sp3)–H with DMF

Xiao-Wen Wang, Yang Deng, Rui-Xue Li, Jin-Feng Lv, Ming-Qiu-Hao Fu, Zhi Guan, Ya-Nan Zhao and Yan-Hong He

ACS Sustainable Chem. Eng., 2023, 11, 1624
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Redox Relay-Induced C–S Radical Cross-Coupling Strategy: Application in Nontraditional Site-Selective Thiocyanation of Quinoxalinones

Shi-Hui Shi, Hao-Yu Li, Hao-Yang Liu, Rui Tian and Hai-Tao Zhu

J. Org. Chem., 2024, 89, 6826
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Electrosynthesis of Thiocyanated/Iodinated/Brominated Pyrazol‐5‐amines and Thiocyanated Enamines via C(sp2)−H Functionalization

Peng Qian, Siqi Jiang, Wenbao Zhang, Hui Zhang, Yuhan Ma, Na Li and Liangquan Sheng

Adv Synth Catal, 2023, 365, 1782
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Electrochemical Benzylic C–H Amination via N-Aminopyridinium

Jingwei Liu, Jinyao Du, Lin-Bao Zhang, Ming Li and Weisi Guo

J. Org. Chem., 2024, 89, 6465
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Electrochemical oxythiocyanation of ortho-olefinic amides: Access to diverse thiocyanated benzoxazines

Shencheng Qian, Pengcheng Xu, Yu Zheng and Shenlin Huang

Tetrahedron Letters, 2023, 116, 154341
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Microwave‐Assisted Metal‐Free C(sp2)−H Thiocyanation of Aromatic Amines

Bhargav Desai, Piyushkumar Satani, Rachit S. Patil, Hussain Bhukya and Togati Naveen

ChemistrySelect, 2023, 8
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Lewis Base Catalyzed C−S Bond Formation Through Methyl C(sp3)‐H Thiocyanation of Indoles

Qumruddeen, Dileep Kumar, Jobsy Jose and Chandra Bhushan Tripathi

Asian J Org Chem, 2024, 13
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Fe(III)‐Mediated para‐Selective Nucleophilic Thiocyanation and Oxidation Reactions, Access to Thiocyanated Amidophenols and Amidoquinones

Ye Yuan, Yibo Liu, HongLing Wang and Xiang Zhang

ChemistrySelect, 2022, 7
DOI: 10.1002/slct.202203719