Aspen X.-Y. Chen, Tanay Kesharwani, Yong Wu, Charlotte L. Stern, Luka Đorđević, Huang Wu, Yu Wang, Bo Song, Liang Feng, Long Zhang, Xingang Zhao, Yang Jiao, Xuesong Li, Han Han, Chun Tang, Ruihua Zhang, Hongliang Chen, Kang Cai, Samuel I. Stupp, Haoyuan Chen, Dengke Shen and J. Fraser Stoddart

Chem, 2024, 10, 234
DOI: 10.1016/j.chempr.2023.08.028

Asymmetric Functionalization Harnessing Radical‐Mediated Functional‐Group Migration

Fushan Chen, Zhu Cao and Chen Zhu

Angew Chem Int Ed, 2025, 64
DOI: 10.1002/anie.202424667

Multipurpose sulfoximine-mediated radical γ-heteroarylation of unactivated C(sp3)-H bonds

Yuqian Sun, Xinxin Wu, Zhu Cao and Chen Zhu

Sci. China Chem., 2023, 66, 1435
DOI: 10.1007/s11426-023-1557-y

Pyridine N-Oxide Mediators for Electrochemical Benzylic C(sp3)–H Oxygenation

Houping Cheng, Yan Liu, Yixiang Ruan, Yuchen He, Xinyu Wang, Jun Xuan, Xiaodong Shen, Ning Ye and Yiming Mo

ACS Electrochem., 2025, 1, 36
DOI: 10.1021/acselectrochem.4c00009

Selective Photocatalytic C−H Oxidation of 5‐Methylcytosine in DNA

Tao Yan, Yuqi Chen, Ben Mortishire‐Smith, Angela Simeone, Alexandre Hofer and Shankar Balasubramanian

Angew Chem Int Ed, 2025, 64
DOI: 10.1002/anie.202413593

Synthesis of Sulfone Methylene-Substituted Indolines by Radical Cascade Cyclization of 2-Alkynylaniline Derivatives

Ning Ma, Yuting Leng, Kaixia Sui, Panpan Wang, Shiliang Jiang and Yangjie Wu

J. Org. Chem., 2024, 89, 10678
DOI: 10.1021/acs.joc.4c00908

Visible‐Light Induced and PIFA Enabled [4+2] Annulation of Alkenes with N‐Aryl Substituted Hydroxamic Acids

Yu‐Zhao Wang, Menglu Jiang, Feng Zhang, Hua‐Wei Zhang, Yue Wu, Wei Yu and Yan Li

Eur J Org Chem, 2024, 27
DOI: 10.1002/ejoc.202400683

Visible‐Light‐Promoted Aliphatic C−H Chlorination and Bromination Using Haloform as the Halogen Donor and Azidobenziodoxole as the Mediator

Qin He, Zehui Cao, Yangyang Zhang, Gong Chen and Yaxin Wang

Adv Synth Catal, 2023, 365, 2711
DOI: 10.1002/adsc.202300416

Redox-active molecules as organocatalysts for selective oxidative transformations – an unperceived organocatalysis field

Elena R Lopat’eva, Igor B Krylov, Dmitry A Lapshin and Alexander O Terent’ev

Beilstein J. Org. Chem., 2022, 18, 1672
DOI: 10.3762/bjoc.18.179

Dualkatalytisch‐Photochemische H‐Atomtransfer/Kobaltkatalysesequenz Ermöglicht Desaturative Synthese von Phenolen aus Cyclohexanonen

Henry P. Caldora, Zhenhua Zhang, Michael J. Tilby, Oliver Turner and Daniele Leonori

Angewandte Chemie, 2023, 135
DOI: 10.1002/ange.202301656

Intramolecular Hydrogen Atom Transfer from Unactivated C(sp3)−H Bond to Alkyl Radical

Huiying Liu, Qihao Jin and Xinxin Wu

Eur J Org Chem, 2024, 27
DOI: 10.1002/ejoc.202301280

Factors Governing Reactivity and Selectivity in Hydrogen Atom Transfer from C(sp3)–H Bonds of Nitrogen-Containing Heterocycles to the Cumyloxyl Radical

Marco Galeotti, Chiara Trasatti, Sergio Sisti, Michela Salamone and Massimo Bietti

J. Org. Chem., 2022, 87, 7456
DOI: 10.1021/acs.joc.2c00955

Development of a HAT Reagent for the Decarboxylative Thiocyanation of Aliphatic Carboxylic Acids

Jordan Vigier, Tatiana Besset and Hélène Lebel

Org. Lett., 2025, 27, 9896
DOI: 10.1021/acs.orglett.5c02821

tert‐Butyl as a Functional Group: Non‐Directed Catalytic Hydroxylation of Sterically Congested Primary C−H Bonds

Siu‐Chung Chan, Andrea Palone, Massimo Bietti and Miquel Costas

Angew Chem Int Ed, 2024, 63
DOI: 10.1002/anie.202402858

Synergistic Copper‐Aminocatalysis for Direct Tertiary α‐Alkylation of Ketones with Electron‐Deficient Alkanes

Qi‐Chao Shan, You‐Wei Wu, Mu‐Xiang Chen, Xuefei Zhao, Teck‐Peng Loh and Xu‐Hong Hu

Advanced Science, 2024, 11
DOI: 10.1002/advs.202402255

Synthesis of New Morphinan Opioids by TBADT‐Catalyzed Photochemical Functionalization at the Carbon Skeleton**

Dmitry Gorbachev, Elliot Smith, Stephen P. Argent, Graham N. Newton and Hon Wai Lam

Chemistry A European J, 2022, 28
DOI: 10.1002/chem.202201478

Accessing α-Amino Ketyl Radicals from β-Amino Alcohols via Chemoselective Hydrogen Atom Transfer Catalysis

Kay Merkens, Nil Sanosa, Ignacio Funes-Ardoiz and Adrián Gómez-Suárez

ACS Catal., 2022, 12, 13186
DOI: 10.1021/acscatal.2c03724

Bromoacetic Acid-Promoted Nonheme Manganese-Catalyzed Alkane Hydroxylation Inspired by α-Ketoglutarate-Dependent Oxygenases

Jie Chen, Jinping Yao, Xiao-Xi Li, Yan Wang, Wenxun Song, Kyung-Bin Cho, Yong-Min Lee, Wonwoo Nam and Bin Wang

ACS Catal., 2022, 12, 6756
DOI: 10.1021/acscatal.2c01096

Electrochemical C(sp3)−H Functionalization Using Acetic Acid as a Hydrogen Atom Transfer Reagent

Yuma Morii, Taito Watanabe, Yutaka Saga, Tetsuya Kambe, Mio Kondo and Shigeyuki Masaoka

ChemElectroChem, 2024, 11
DOI: 10.1002/celc.202400061

The Merger of Benzophenone HAT Photocatalysis and Silyl Radical-Induced XAT Enables Both Nickel-Catalyzed Cross-Electrophile Coupling and 1,2-Dicarbofunctionalization of Olefins

Alberto Luridiana, Daniele Mazzarella, Luca Capaldo, Juan A. Rincón, Pablo García-Losada, Carlos Mateos, Michael O. Frederick, Manuel Nuño, Wybren Jan Buma and Timothy Noël

ACS Catal., 2022, 12, 11216
DOI: 10.1021/acscatal.2c03805

Cysteine Radical and Glutamate Collaboratively Enable C–H Bond Activation and C–N Bond Cleavage in a Glycyl Radical Enzyme HplG

Wen-Hao Deng and Rong-Zhen Liao

J. Chem. Inf. Model., 2024, 64, 4168
DOI: 10.1021/acs.jcim.4c00122

Recent Advances in Asymmetric Transformations of Unactivated Alkanes and Cycloalkanes through Direct C—H Functionalization

Shiyan Cheng, Qianyu Li, Xiuliang Cheng, Yu‐Mei Lin and Lei Gong

Chin. J. Chem., 2022, 40, 2825
DOI: 10.1002/cjoc.202200435

Hydrogen Bonding-Assisted and Nonheme Manganese-Catalyzed Remote Hydroxylation of C–H Bonds in Nitrogen-Containing Molecules

Jie Chen, Wenxun Song, Jinping Yao, Zhimin Wu, Yong-Min Lee, Yong Wang, Wonwoo Nam and Bin Wang

J. Am. Chem. Soc., 2023, 145, 5456
DOI: 10.1021/jacs.2c13832

A Decarbonylative Strategy to Enhance Efficiency and Regioselectivity in Photocatalyzed Hydrogen Atom Transfer

Elena Cassera, Vittoria Martini, Valerio Morlacci, Serena Abrami, Nicola Della Ca’, Davide Ravelli, Maurizio Fagnoni and Luca Capaldo

JACS Au, 2025, 5, 3491
DOI: 10.1021/jacsau.5c00530

Metal‐Free Electrochemical C─H Chlorination of Terminal Alkanes

Qingxu Wang, Pengkai Fang, Jianyou Zhao, Xianting Huang, Xiaoqian Shen, Fan Wang and Zhong‐Quan Liu

Angew Chem Int Ed, 2025, 64
DOI: 10.1002/anie.202504478

Site- and enantioselective cross-coupling of saturated N-heterocycles with carboxylic acids by cooperative Ni/photoredox catalysis

Xiaomin Shu, De Zhong, Qian Huang, Leitao Huan and Haohua Huo

Nat Commun, 2023, 14
DOI: 10.1038/s41467-023-35800-0

Enhanced Reactivity of Acridinium Perchlorate: Harnessing Redox Mediators for Trace Chloride Activation in Hydrogen Atom Transfer Photocatalysis

Mingyue Wu, Zugen Wu, Hwee Ting Ang, Bing Wang, Tao Liu, Shaofei Wu, Zhexuan Lei, Ming Wai Liaw, Supphachok Chanmungkalakul, Chi-Lik Ken Lee, Xiaogang Liu, Yixin Lu and Jie Wu

ACS Catal., 2024, 14, 9364
DOI: 10.1021/acscatal.4c01910

Photoinduced decatungstate-catalyzed direct coupling of cycloalkanes and cyclic aldimines

Jingjing Wang, Feng Li, Kai Liu, Chong Li, Sheng Cao, Yuxiang Wu, Yongjun Yuan, Fei Teng, Teng Wang and Yao Zhou

Green Synthesis and Catalysis, 2024, 5, 315
DOI: 10.1016/j.gresc.2023.10.002

Understanding the Origins of Site Selectivity in Hydrogen Atom Transfer Reactions from Carbohydrates to the Quinuclidinium Radical Cation: A Computational Study

Julia A. Turner, Timur Adrianov and Mark S. Taylor

J. Org. Chem., 2023, 88, 5713
DOI: 10.1021/acs.joc.3c00181

Hydrogen‐Bonding‐Driven Site‐Selective Activation of α‐C(sp3)─H in Alcohols: A Straightforward Dual‐Catalysis Strategy for Efficient Acceptorless Dehydrogenation

Bin Sun, Shuangshuang Zhou, Jiayin Wang, Xuejing Xu, Xiaohui Zhuang, Weike Su and Can Jin

Angewandte Chemie, 2025, 137
DOI: 10.1002/ange.202506022

Oxoammonium-Catalyzed Ether Oxidation via Hydride Abstraction: Methodology Development and Mechanistic Investigation Using Paramagnetic Relaxation Enhancement NMR

Yukun Cheng, Jonas Rein, Nguyen Le and Song Lin

J. Am. Chem. Soc., 2024, 146, 31420
DOI: 10.1021/jacs.4c11760

Research progress on visible-light-induced C–H functionalization reactions catalyzed by covalent organic frameworks

Yu Chen, Yuezhu Qi, Runzhe Wu, Yitong Pan, Guoqing Huang, Ming Yang, Xiubin Bu, Xiaobo Yang and Zhen Zhao

Sci. Sin.-Chim, 2025, 55, 1879
DOI: 10.1360/SSC-2024-0266

Three‐Component Radical Cascade Reaction of Quinoxalinones, Alkenes and AgSCF3

Sha Peng, Long‐Yong Xie and Luo Yang

Adv Synth Catal, 2023, 365, 3328
DOI: 10.1002/adsc.202300630

Photoelectrochemical Cerium Catalysis via Ligand-to-Metal Charge Transfer: A Rising Frontier in Sustainable Organic Synthesis

Yuying Wang, Siyuan Liu, Jiangsheng Han, Ling Wang and Jianbin Chen

Synthesis, 2023, 55, 2860
DOI: 10.1055/a-2044-2140

Late-Stage Heteroarene Alkylation via Minisci Reaction with Gaseous Alkanes Enabled by Hydrogen Atom Transfer in Flow

Prakash Chandra Tiwari, Antonio Pulcinella, Emil Hodžić and Timothy Noël

ACS Cent. Sci., 2025, 11, 910
DOI: 10.1021/acscentsci.5c00468

tert‐Butyl as a Functional Group: Non‐Directed Catalytic Hydroxylation of Sterically Congested Primary C−H Bonds

Siu‐Chung Chan, Andrea Palone, Massimo Bietti and Miquel Costas

Angewandte Chemie, 2024, 136
DOI: 10.1002/ange.202402858

Carbonylation Reactions at Carbon‐Centered Radicals with an Adjacent Heteroatom

Le‐Cheng Wang and Xiao‐Feng Wu

Angew Chem Int Ed, 2024, 63
DOI: 10.1002/anie.202413374

Asymmetric Functionalization Harnessing Radical‐Mediated Functional‐Group Migration

Fushan Chen, Zhu Cao and Chen Zhu

Angewandte Chemie, 2025, 137
DOI: 10.1002/ange.202424667

Synthetic Applications of Photocatalyzed Halogen‐Radical Mediated Hydrogen Atom Transfer for C−H Bond Functionalization

Stefano Bonciolini, Timothy Noël and Luca Capaldo

Eur J Org Chem, 2022, 2022
DOI: 10.1002/ejoc.202200417

Light‐induced FeCl3‐catalyzed selective benzyl C−H chlorination with trifluoromethanesulfonyl chloride

Chen‐Xi Yang, De‐Guang Liu, Li‐Juan Li, Yu‐Xing Zhang, Xi‐Rui Xia, Hong Jiang and Wan‐Min Cheng

Adv Synth Catal, 2023, 365, 4144
DOI: 10.1002/adsc.202300672

Carbonylation Reactions at Carbon‐Centered Radicals with an Adjacent Heteroatom

Le‐Cheng Wang and Xiao‐Feng Wu

Angewandte Chemie, 2024, 136
DOI: 10.1002/ange.202413374

Electrochemical Allylic C(sp3)–H Isothiocyanation via [3,3]-Sigmatropic Rearrangement

Xuezhuang Gao, Hui He, Kaili Miao, Linbao Zhang, Shao-Fei Ni, Ming Li and Weisi Guo

Org. Lett., 2024, 26, 4554
DOI: 10.1021/acs.orglett.4c01463

Application of Molecular Ferroelectric in Photocatalytic Selective Oxidization of C(sp3)─H Bonds

Huihui Hu, Rong Liu, Yan‐Bing Zhu, Tai‐Ting Sha, Xiao‐Xing Cao, Zi‐Jie Feng, Hao‐Ran Ji, Qiang Pan, Ren‐Gen Xiong and Yu‐Meng You

Angewandte Chemie, 2025, 137
DOI: 10.1002/ange.202500176

Photoredox Catalytic Approach for Difluoroallylation of Electron-Deficient sp3 C–H Bonds

Xin-Lu Fan, Zi-Yan Wang, Wei Shi, Zi-Jun Luo, Xuefei Zhao and Xu-Hong Hu

Org. Lett., 2025, 27, 8607
DOI: 10.1021/acs.orglett.5c02542

Photochemical Deracemization of Lactams with Deuteration Enabled by Dual Hydrogen Atom Transfer

Xiaoyu Yan, Yubing Pang, Yutong Zhou, Rui Chang and Juntao Ye

J. Am. Chem. Soc., 2025, 147, 1186
DOI: 10.1021/jacs.4c14934

Manganese-Catalyzed Regioselective C–H Lactonization and Hydroxylation of Fatty Acids with H2O2

Vladimir I. Kurganskiy, Roman V. Ottenbacher, Mikhail V. Shashkov, Evgenii P. Talsi, Denis G. Samsonenko and Konstantin P. Bryliakov

Org. Lett., 2022, 24, 8764
DOI: 10.1021/acs.orglett.2c03458

Polar Heterobenzylic C(sp3)–H Chlorination Pathway Enabling Efficient Diversification of Aromatic Nitrogen Heterocycles

Soham Maity, Marco A. Lopez, Desiree M. Bates, Shishi Lin, Shane W. Krska and Shannon S. Stahl

J. Am. Chem. Soc., 2023, 145, 19832
DOI: 10.1021/jacs.3c05822

Photoinduced Hydrogen Atom Transfer Activation of Benzylic C−H Bonds Functionalization

Guozhe Guo and Wenduo Li

Adv Synth Catal, 2025, 367
DOI: 10.1002/adsc.202401266

Recent Advances in Hydrogen Atom Transfer Induced Selective C(sp3)—H Functionalization of Alkanes

Miao Wang, Yahao Huang and Peng Hu

Chinese Journal of Organic Chemistry, 2025, 45, 477
DOI: 10.6023/cjoc202407027

Photoinduced PhI(OAc)2-Mediated Cross-Dehydrogenative Heteroarylation of Aldehydes

Lusina Mantry and Parthasarathy Gandeepan

J. Org. Chem., 2025, 90, 6897
DOI: 10.1021/acs.joc.5c00655

Digital Photoinduced Topographical Microsculpting of Hydrogels

Maaike Bril, Mirko D'Urso, Mario Prejanò, Matteo Costantini, Livia Angeloni and Nicholas A. Kurniawan

Adv Materials Technologies, 2024, 9
DOI: 10.1002/admt.202400721

Deconstructive Radical–Radical Coupling for Programmable Remote Acylation

Jing Cao, Cullen R. Schull and Karl A. Scheidt

Angewandte Chemie, 2025, 137
DOI: 10.1002/ange.202507542

Rapid Access to 2-Substituted Bicyclo[1.1.1]pentanes

Olivia L. Garry, Michael Heilmann, Jingjia Chen, Yufan Liang, Xiaheng Zhang, Xiaoshen Ma, Charles S. Yeung, David Jonathan Bennett and David W. C. MacMillan

J. Am. Chem. Soc., 2023, 145, 3092
DOI: 10.1021/jacs.2c12163

Enhanced Efficiency of Amide‐Substituted Quinuclidine‐Boranes as Hydridic Hydrogen Atom Transfer Catalysts for Photoinduced Hydroalkylation of Unactivated Olefins†

Xiao Yang, Mengdi Ma, Meichen Xu, Yubing Pang, Haiying Zhao and Juntao Ye

Chin. J. Chem., 2024, 42, 3227
DOI: 10.1002/cjoc.202400725

Radical and Cationic Pathways in C(sp3)–H Bond Oxygenation by Dioxiranes of Bicyclic and Spirocyclic Hydrocarbons Bearing Cyclopropane Moieties

Marco Galeotti, Woojin Lee, Sergio Sisti, Martina Casciotti, Michela Salamone, K. N. Houk and Massimo Bietti

J. Am. Chem. Soc., 2023, 145, 24021
DOI: 10.1021/jacs.3c07163

Visible-Light-Mediated Cascade 1,4-Hydrogen Atom Transfer versus Dearomative Spirocyclization of N-Benzylacrylamides: Divergent Access to Functionalized γ-Ketoamides and 2-Azaspiro[4.5]decanes

Chandra Shekhar Nishad, Ashish Kumar, Kamaldeep Kaur and Biplab Banerjee

J. Org. Chem., 2025, 90, 1411
DOI: 10.1021/acs.joc.4c02862

Direct Alkylation of Glycine Derivatives via Photoinduced Palladium Catalysis, Utilizing Intermolecular Hydrogen Atom Transfer Mediated by Alkyl Radicals

Sen Yang, Hao Hu, Jun-hua Li and Ming Chen

ACS Catal., 2023, 13, 15652
DOI: 10.1021/acscatal.3c04075

Catalytic manipulation of reversibility and irreversibility in a supramolecular reaction network to control the self-assembly outcome

Tsukasa Abe, Satoshi Takahashi, Runyu Chai, Hirofumi Sato and Shuichi Hiraoka

Chem, 2025, 102741
DOI: 10.1016/j.chempr.2025.102741

Organophotoredox and Hydrogen Atom Transfer Cocatalyzed C–H Alkylation of Quinoxalin-2(1H)-ones with Aldehydes, Amides, Alcohols, Ethers, or Cycloalkanes

Liling Wang, Zhaoxing Chen, Guohua Fan, Xiaozu Liu and Peijun Liu

J. Org. Chem., 2022, 87, 14580
DOI: 10.1021/acs.joc.2c01967

RHAT‐Enabled Deoxyfunctionalization of Cyclic Acetals Derived from Vicinal Diols

Zheng Wang, Huiying Liu, Tiantian Liu, Qixiang Wang, Zhaoshan Wang, Dong Chen, Shun‐Yi Wang, Xiaoguang Bao and Xinxin Wu

Chemistry An Asian Journal, 2025, 20
DOI: 10.1002/asia.202500642

Phosphonium Ylide as Hydrogen Atom Transfer Catalyst Platform Based on Carbon-Centered Radical with High Structural Tunability

Joaquim Caner, Natsumi Maeda, Daisuke Yokogawa, Akira Matsumoto and Keiji Maruoka

JACS Au, 2025, 5, 2463
DOI: 10.1021/jacsau.5c00400

Site-selective 2° C-H chlorination of alkane by metal-free electrochemistry

Quanjin Rong, Qingxu Wang, Jianyou Zhao, Zhe Zhang, Xuan Huang, Fan Wang and Zhong-Quan Liu

Sci. China Chem., 2025
DOI: 10.1007/s11426-025-2830-6

C−H Bond Activation Relay (CHAR) of Proline Ester Derivatives Promoted by In Situ Triarylamine Radical Cation: Selective Synthesis of 4‐Bromopyrrole Derivatives

Han Ding, Shuwei Zhang, Zheng Sun, Qiyuan Ma, Yuemei Li, Yu Yuan and Xiaodong Jia

Chemistry A European J, 2023, 29
DOI: 10.1002/chem.202203654

Radical‐Mediated Selective Functionalization of Unactivated Primary C—H Bonds

Zhan‐Lin Wang and Fei Wang

Chin. J. Chem., 2022, 40, 1751
DOI: 10.1002/cjoc.202200210

Visible-Light-Catalyzed Tandem Radical Addition/1,5-Hydrogen Atom Transfer/Cyclization of 2-Alkynylarylethers with Sulfonyl Chlorides

Long Li, Jiao-Zhe Li, Yong-Bin Sun, Chun-Mei Luo, Hui Qiu, Keqi Tang, Hongxin Liu and Wen-Ting Wei

Org. Lett., 2022, 24, 4704
DOI: 10.1021/acs.orglett.2c01977

Electrochemical Trifluoromethylation/1,5-HAT Reaction of N-Cyanamide Alkenes: Synthesis of Trifluoromethylated Cyclic Amidines and N-Acryloylpyrrolidin-2-one Derivatives

Zhihua Yan, Zhonglin Wei, Yan Yan and Wei-Wei Liao

J. Org. Chem., 2025, 90, 13116
DOI: 10.1021/acs.joc.5c01733

Photochemical Allylation of Alkanes Enabled by Nickel Catalysis

Youxiang Jin, Elvis Wang Hei Ng, Tao Fan, Hajime Hirao and Liu-Zhu Gong

ACS Catal., 2022, 12, 10039
DOI: 10.1021/acscatal.2c02345

Metal‐Free Electrochemical C─H Chlorination of Terminal Alkanes

Qingxu Wang, Pengkai Fang, Jianyou Zhao, Xianting Huang, Xiaoqian Shen, Fan Wang and Zhong‐Quan Liu

Angewandte Chemie, 2025, 137
DOI: 10.1002/ange.202504478

Unlocking the Nucleophilicity of Strong Alkyl C–H Bonds via Cu/Cr Catalysis

Pan Peng, Yifan Zhong, Cong Zhou, Yongsheng Tao, Dandan Li and Qingquan Lu

ACS Cent. Sci., 2023, 9, 756
DOI: 10.1021/acscentsci.2c01389

Enzymatic and Bio-Inspired Enantioselective Oxidation of Non-Activated C(sp 3)–H Bonds

Andrea Palone, Massimo Bietti and Miquel Costas

Synthesis, 2025, 57, 1280
DOI: 10.1055/a-2403-0760

Radical Polarity

Jacob J. A. Garwood, Andrew D. Chen and David A. Nagib

J. Am. Chem. Soc., 2024
DOI: 10.1021/jacs.4c06774

Regioselective aliphatic C–H functionalization using frustrated radical pairs

Zhipeng Lu, Minsoo Ju, Yi Wang, Jonathan M. Meinhardt, Jesus I. Martinez Alvarado, Elisia Villemure, Jack A. Terrett and Song Lin

Nature, 2023, 619, 514
DOI: 10.1038/s41586-023-06131-3

Unveiling the Delicate Balance of Polarity and Strain Effect in Determining the Site-Selective Intramolecular Hydrogen Atom Transfers

Zhonghua Hao, Wenna Ai and Neil Qiang Su

J. Phys. Chem. A, 2025, 129, 4969
DOI: 10.1021/acs.jpca.5c00340

O2 Activation by a Coordinated −NH– Function: Hydrogen Atom Transfer and Aromatic Ring Oxidation

Souvik Mukherjee, Sandip Mondal and Prasanta Ghosh

Inorg. Chem., 2023, 62, 21147
DOI: 10.1021/acs.inorgchem.3c03038

Advances in Palladium-Catalyzed C(sp3)–H Functionalization: The Role of Traceless Directing Groups

Masoud Sadeghi

ACS Catal., 2024, 14, 15356
DOI: 10.1021/acscatal.4c04801

Deconstructive Radical–Radical Coupling for Programmable Remote Acylation

Jing Cao, Cullen R. Schull and Karl A. Scheidt

Angew Chem Int Ed, 2025, 64
DOI: 10.1002/anie.202507542

Selective Photocatalytic C−H Oxidation of 5‐Methylcytosine in DNA

Tao Yan, Yuqi Chen, Ben Mortishire‐Smith, Angela Simeone, Alexandre Hofer and Shankar Balasubramanian

Angewandte Chemie, 2025, 137
DOI: 10.1002/ange.202413593

Heterocoupling Two Similar Benzyl Radicals by Dual Photoredox/Cobalt Catalysis

Wei Yang, Zhenyan Zhao, Yu Lan, Zhou Dong, Ruiying Chang, Yihang Bai, Shihan Liu, Shi‐Jun Li and Linbin Niu

Angewandte Chemie, 2025, 137
DOI: 10.1002/ange.202421256

Dual Photochemical H‐Atom Transfer and Cobalt Catalysis for the Desaturative Synthesis of Phenols from Cyclohexanones

Henry P. Caldora, Zhenhua Zhang, Michael J. Tilby, Oliver Turner and Daniele Leonori

Angew Chem Int Ed, 2023, 62
DOI: 10.1002/anie.202301656

Photoinduced Nitroarenes as Versatile Anaerobic Oxidants for Accessing Carbonyl and Imine Derivatives

Joshua K. Mitchell, Waseem A. Hussain, Ajay H. Bansode, Ryan M. O’Connor, Dan E. Wise, Michael H. Choe and Marvin Parasram

Org. Lett., 2023, 25, 6517
DOI: 10.1021/acs.orglett.3c02292

Application of Molecular Ferroelectric in Photocatalytic Selective Oxidization of C(sp3)─H Bonds

Huihui Hu, Rong Liu, Yan‐Bing Zhu, Tai‐Ting Sha, Xiao‐Xing Cao, Zi‐Jie Feng, Hao‐Ran Ji, Qiang Pan, Ren‐Gen Xiong and Yu‐Meng You

Angew Chem Int Ed, 2025, 64
DOI: 10.1002/anie.202500176

Strain Release in Hydrogen Atom Transfer from 1,4-Disubstituted Cyclohexanes to the Cumyloxy Radical

Marco Galeotti, Andrea Palone, Michela Salamone, Fengjiao Liu, Yanmin Yu, K. N. Houk and Massimo Bietti

Synlett, 2025, 36, 1579
DOI: 10.1055/a-2522-6204

Studies on Inert-Alkane Oxidation Systems with Reactive-Oxygen Transition-Metal Complexes

祐麻森本 and Yuma Morimoto

Bull. Jpn. Soc. Coord. Chem., 2025, 85, 49
DOI: 10.4019/bjscc.85.49

Recent Advances on C—H Functionalization via Oxidative Electrophotocatalysis

Aman Hasil, Rui Chang and Juntao Ye

Chinese Journal of Organic Chemistry, 2024, 44, 728
DOI: 10.6023/cjoc202311032

Photoelectrochemical C−H Activation Through a Quinacridone Dye Enabling Proton‐Coupled Electron Transfer

Yunshuo Yang, Giulia Alice Volpato, Elena Rossin, Nicola Peruffo, Francesco Tumbarello, Catia Nicoletti, Ruggero Bonetto, Lorenzo Paoloni, Paolo Umari, Elena Colusso, Luca Dell'Amico, Serena Berardi, Elisabetta Collini, Stefano Caramori, Stefano Agnoli and Andrea Sartorel

ChemSusChem, 2023, 16
DOI: 10.1002/cssc.202201980

C1‐4 Alkylation of Aryl Bromides with Light Alkanes enabled by Metallaphotocatalysis in Flow

Antonio Pulcinella, Prakash Chandra Tiwari, Alberto Luridiana, Ken Yamazaki, Daniele Mazzarella, Akshay K. Sadhoe, Antonella Ilenia Alfano, Eveline H. Tiekink, Trevor A. Hamlin and Timothy Noël

Angewandte Chemie, 2025, 137
DOI: 10.1002/ange.202413846

Enantioselective Total Syntheses of (+)-Kobusine, (+)-Spirasine IX and the Purported Structure of (+)-Orgetine: Strategic Use of C–H Bonds

Mengping Deng, Fanrui Wu, Tianran Liu, Zhe Jiang and Tuoping Luo

J. Am. Chem. Soc., 2025, 147, 8132
DOI: 10.1021/jacs.5c00650

Oxidative Alkylarylation of N‐Aryl Bicyclobutyl Amides with C(sp3)–H Feedstocks via C(sp3)–H/C(sp2)–H Functionalization

Jing Yuan, Jiao Zhou, Peng‐Fei Xia, Yu Liu, Ke‐Wen Tang and Jian‐Hong Fan

Chin. J. Chem., 2024, 42, 3399
DOI: 10.1002/cjoc.202400748

C1‐4 Alkylation of Aryl Bromides with Light Alkanes enabled by Metallaphotocatalysis in Flow

Antonio Pulcinella, Prakash Chandra Tiwari, Alberto Luridiana, Ken Yamazaki, Daniele Mazzarella, Akshay K. Sadhoe, Antonella Ilenia Alfano, Eveline H. Tiekink, Trevor A. Hamlin and Timothy Noël

Angew Chem Int Ed, 2025, 64
DOI: 10.1002/anie.202413846

Strategies and Mechanisms of First-Row Transition Metal-Regulated Radical C–H Functionalization

Xinghua Wang, Jing He, Ya-Nan Wang, Zhenyan Zhao, Kui Jiang, Wei Yang, Tao Zhang, Shiqi Jia, Kangbao Zhong, Linbin Niu and Yu Lan

Chem. Rev., 2024, 124, 10192
DOI: 10.1021/acs.chemrev.4c00188

Recent Advances in C–H Functionalisation through Indirect Hydrogen Atom Transfer

Filip S. Meger and John A. Murphy

Molecules, 2023, 28, 6127
DOI: 10.3390/molecules28166127