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Abstract | Cited by

Electronic couplings in a 1,3-butadiyne-bridged Zn(II) porphyrin dimer D and trimer T have been probed by measuring their excited-state properties at ensemble and single molecular levels. While single chromophore-like, strongly interacting behaviors are revealed for D, the coupling in T is indicated to be not so strong.

Graphical abstract: Excited-state electronic couplings in a 1,3-butadiyne-bridged Zn(ii)porphyrin dimer and trimer

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