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Abstract | Cited by

The tandem Crabbé homologation-radical rearrangement of terminal enediynes leads, in a one-pot procedure, to the enantioselective synthesis of six- and seven-membered ring α-aminoesters bearing a quaternary stereocenter based on the phenomenon of memory of chirality.

Graphical abstract: One-pot Crabbé homologation-radical cascade cyclisation with memory of chirality

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