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DOI: 10.1039/A809184F (Paper) Reference Section for: Chem. Commun., 1999, 373-374

Thiacalixarenes as cluster keepers: synthesis and structural analysis of a magnetically coupled tetracopper(II) square

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Gilles Mislin, Ernest Graf, Mir Wais Hosseini, Alexander Bilyk, Annegret K. Hall, Jack M. Harrowfield, Brian W. Skelton and Allan H. White

Abstract

An X-ray structure determination of an antiferromagnetic copper complex of p-tert-butyltetrathiacalix[4]arene has shown it to contain a square, phenoxo- and sulfur-bridged cluster of four Cu(II) ions sandwiched between two fully deprotonated calixarenes, thus forming a ditopic, divergent receptor; as prepared, the complex has each cavity occupied by a molecule of dichloromethane.

References

  1. M. W. Hosseini and A. De Cian, Chem. Commun., 1998, 727 RSC.
  2. C. D. Gutsche, Calixarenes Revisited, Monographs in Supramolecular Chemistry, No. 1, ed. J. F. Stoddart, RSC, Cambridge, 1998 Search PubMed.
  3. X. Delaigue, M. W. Hosseini, A. De Cian, J. Fischer, E. Leize, S. Kieffer and A. Van Dorsselaer, Tetrahedron Lett., 1993, 34, 3285 CrossRef CAS.
  4. M. M. Olmstead, G. Sigel, H. Hope, X. Xu and P. Power, J. Am. Chem. Soc., 1985, 107, 8087 CrossRef CAS; F. Corazza, C. Floriani, A. Chiesi-Villa and C. Guastini, J. Chem. Soc., Chem. Commun., 1990, 1083 RSC; J. L. Atwood, S. G. Bott, C. Jones and C. L. Raston, J. Chem. Soc., Chem. Commun., 1992, 1349 RSC; J. L. Atwood, P. C. Junk, S. M. Lawrence and C. L. Raston, Supramol. Chem., 1996, 7, 15 CrossRef CAS; A. Bilyk, J. M. Harrowfield, B. W. Skelton and A. H. White, J. Chem. Soc., Dalton Trans, 1997, 4251 RSC and references therein..
  5. X. Delaigue, J. M. Harrowfield, M. W. Hosseini, A. De Cian, J. Fischer and N. Kyritsakas, J. Chem. Soc., Chem. Commun., 1994, 1579 RSC; X. Delaigue, M. W. Hosseini, N. Kyritsakas, A. De Cian and J. Fischer, J. Chem. Soc., Chem. Commun., 1995, 609 RSC; X. Delaigue, J. M. Harrowfield, M. W. Hosseini, M. Mocerino, B. W. Skelton and A. H. White, Aust. J. Chem., 1998, 51, 111 CAS.
  6. D. M. Roundhill, Prog. Inorg. Chem., 1995, 43, 533 CAS.
  7. H. Kumagai, M. Hasegawa, S. Miyanari, Y. Sugawa, Y. Sato, T. Hori, S. Ueda, H. Kamiyama and S. Miyano, Tetrahedron Lett., 1997, 38, 3971 CrossRef CAS; T. Sone, Y. Ohba, K. Moriya, H. Kumada and K. Ito, Tetrahedron Lett., 1997, 38, 10689.
  8. H. Akdas, L. Bringel, E. Graf, M. W. Hosseini, G. Mislin, J. Pansanel, A. De Cian and J. Fischer, Tetrahedron Lett., 1998, 39, 2311 CrossRef CAS.
  9. G. Mislin, E. Graf, M. W. Hosseini, A. De Cian and J. Fischer, Chem. Commun., 1998, 1345 RSC.
  10. N. Iki, H. Kumagai, N. Morohashi, K. Ajima, M. Hasegawa and S. Miyano, Tetrahedron Lett., 1998, 39, 7559 CrossRef CAS.
  11. G. Mislin, E. Graf, M. W. Hosseini, A. De Cian and J. Fischer, Tetrahedron Lett., 1998, 39 submitted..
  12. J. M. Harrowfield, M. I. Ogden, W. R. Richmond and A. H. White, J. Chem. Soc., Chem. Commun., 1991, 1159 RSC; R. Asmuss, V. Böhmer, J. M. Harrowfield, M. I. Ogden, W. R. Richmond, B. W. Skelton and A. H. White, J. Chem. Soc., Dalton Trans., 1993, 2427 RSC.
  13. E. I. Solomon, U. M. Sundaram and T. E. Machonkin, Chem. Rev., 1996, 96, 2563 CrossRef CAS.
  14. P. Chaudhuri, I. Karpenstein, M. Winter, M. Lengen, C. Butzlaff, E. Bill, A. X. Trautwein, U. Flöcke and H.-J. Haupt, Inorg. Chem., 1993, 32, 888 CrossRef.
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