Innovations in isocyanate synthesis for a sustainable future

Jorge Andrés Mora Vargas, Ketan S. Mandrekar, Radell Echemendía and Antonio C. B. Burtoloso

Org. Biomol. Chem., 2025, 23, 487
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From a humorous post to a detailed quantum-chemical study: isocyanate synthesis revisited

Oleg B. Beletsan, Igor Gordiy, Sergey S. Lunkov, Mikhail A. Kalinin, Larisa E. Alkhimova, Egor A. Nosach, Egor A. Ilin, Alexandr V. Bespalov, Olgert L. Dallakyan, Aleksandr A. Chamkin, Ilya V. Prolomov, Radion A. Zaripov, Andrey A. Pershin, Bogdan O. Protsenko, Yury V. Rusalev, Ruslan A. Oganov, Diana K. Kovaleva, Vladimir A. Mironov, Victor V. Dotsenko, Alexandr M. Genaev, Dmitry I. Sharapa and Denis S. Tikhonov

Phys. Chem. Chem. Phys., 2024, 26, 13850
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Studies on poly(butylene succinate) and poly(butylene succinate-co-adipate)-based biodegradable plastics for sustainable flexible packaging and agricultural applications: a comprehensive review

Debarshi Nath, Manjusri Misra, Fadi Al-Daoud and Amar K. Mohanty

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A novel method for the green synthesis of biobased hexamethylene-1,6-dicarbamate

Yunhan Bai, Dule Huhe, Xinyu Du, Yucong Song, Xiaoshu Ding, Dongsheng Zhang, Xinqiang Zhao and Yanji Wang

Green Chem., 2024, 26, 11636
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Synthesis of CO2-based biomass derived non-isocyanate polyurethane hybrid adhesives with excellent mechanical properties and water resistance

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Green Chem., 2025, 27, 2102
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Integrated technoeconomic and environmental assessment of biogenic polyurethane production

Alberto Almena, Domenico Pirone, Susana Fernández-Prieto, Alberto Martínez and Mariano Martin

Green Chem., 2025, 27, 5507
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Cutting-edge development of non-isocyanate polyurethane (NIPU) foams: from sustainable precursors to environmental impact evaluation

Federica Orabona, Federica Recupido, Giuseppe Cesare Lama, Krzysztof Polaczek, Francesco Taddeo, Tapio Salmi, Martino Di Serio, Letizia Verdolotti and Vincenzo Russo

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Cyclizative dearomative rearrangement of pyridines with isocyanates

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A review on vegetable oil-based non isocyanate polyurethane: towards a greener and sustainable production route

Marwah Rayung, Noraini Abd Ghani and Norhafizah Hasanudin

RSC Adv., 2024, 14, 9273
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Polyols from cashew nut shell liquid (CNSL): corner-stone building blocks for cutting-edge bio-based additives and polymers

Emilie Rojtman, Maxinne Denis, Camille Sirvent, Vincent Lapinte, Sylvain Caillol and Benoit Briou

Polym. Chem., 2024, 15, 4375
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Phosphate functionalized nonisocyanate polyurethanes with bio-origin, water solubility and biodegradability

Eric Kwok Wai Tam, Ning Xi Chong, Ping Sen Choong, Barindra Sana, Abdul Majeed Seayad, Satyasankar Jana and Jayasree Seayad

Green Chem., 2024, 26, 1007
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Catalytic synthesis of bio-based carbamate by methoxycarbonylation of furfurylamine with dimethyl carbonate over Pb–Ni composite oxides

Zihao Bu, Kuo Zhou, Jialin Xu, Yuhao Wu and Shengrong Guo

React. Chem. Eng., 2025
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Environmental benefits of valorising food waste into bio-based polyols for the production of polyurethane rigid foams

Zi-Hao Qin, Anda Fridrihsone, Liang Dong, Jin-Hua Mou, Yahui Miao, Lin Zhang, Chunbao Xu, Mikelis Kirpluks and Carol Sze Ki Lin

Sustainable Production and Consumption, 2024, 51, 572
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How To Get Isocyanate?

Zhuhua Guo, Xiaoshu Ding and Yanji Wang

ACS Omega, 2024, 9, 11168
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Sustainability in polyurethanes: old hat or new strategy for future developments?

Giulio Malucelli and Alessandra Lorenzetti

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Towards sustainable catalyst-free biomass-based polyurethane-wood composites (PU-WC): From valorization and liquefaction to future generation of biocomposites

Adam Olszewski, Paulina Kosmela and Łukasz Piszczyk

Journal of Cleaner Production, 2024, 468, 143046
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Ring-closing-opening Copolymerization of Phthalaldehyde and Epoxide towards Acid-degradable Polyether and Polyurethane

Jie Pang, Yu-Bo Zhou, Li-Jun Liu, Hong-Xin Zhang and Jun-Peng Zhao

Chin J Polym Sci, 2025, 43, 964
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Nonconjugated Polyurethane Derivatives with Aggregation-Induced Luminochromism for Multicolor and White Photoluminescent Films

Nan Jiang, Ya-Jie Meng, Chang-Yi Zhu, Ke-Xin Li, Xin Li, Yan-Hong Xu, Jia-Wei Xu and Martin R. Bryce

ACS Macro Lett., 2024, 13, 1226
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Recycling of Polyurethane Foams via Glycolysis: A Review

Kinga Wieczorek, Przemysław Bukowski, Krystian Stawiński and Iwona Ryłko

Materials, 2024, 17, 4617
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Effect of Dual Curing Agent (TDI:DDI) on the Mechanical Properties and Burning Rate of HTPB-Based Solid Propellant

Mohammad Javad Sotoudeh Kheirabadi, Hossein Fakhraian and Mohammad Javad Taghizadeh

Combustion Science and Technology, 2024, 1
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Nonconventional Full-Color Luminescent Polyurethanes: Luminescence Mechanism at the Molecular Orbital Level

Nan Jiang, Ya-Jie Meng, Xin Pu, Chang-Yi Zhu, Shu-Han Tan, Yan-Hong Xu, You-Liang Zhu, Jia-Wei Xu and Martin R. Bryce

ACS Materials Lett., 2025, 7, 24
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Non-isocyanate polyurethane (NIPU) Foams: Overcoming challenges and embracing sustainability

Pooja Singh, Manpreet Kour, Gunjan Varshney and Raminder Kaur

Polymer, 2025, 333, 128658
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Development and Characterization of a Cationic Polyurethane Carrier for Enhanced Topical DNA Delivery

Florin Borcan, Adel Len, Titus Vlase, Gabriela Vlase, Zoltan Dudas, Roxana Popescu, Ramona Albulescu, Cristina Dehelean and Camelia Szuhanek

DDDT, 2025, Volume 19, 5781
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Recent Advances in Polyurethane for Artificial Vascular Application

Hua Ji, Xiaochen Shi and Hongjun Yang

Polymers, 2024, 16, 3528
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Thermally Switchable Chitosan-Polycarbamate Cross-linked Epoxy Resin Composites with Enhanced Mechanical Strength and UV-A Shielding

Elavazhagan Gunasekaran, Vasam Sumalatha and Sankar Govindarajan

Ind. Eng. Chem. Res., 2025, 64, 8211
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Advanced Silver Ion Exchange‐Based Hydrophilic Antimicrobial PU Foams: Synthesis and Comprehensive In Vitro Characterizations

Jay Hind Rajput, Varun Rathi, Anwesha Mukherjee, Pankaj Yadav, Tarush Gupta, Bodhisatwa Das and Atharva Poundarik

Journal of Polymer Science, 2025
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Carbon dioxide‐based poly(hydroxyurethane‐urea) elastomers: Synthesis, microphase structure, and properties

Shan Jiang, Tianyi Han, Tongshuai Tian, Chuanqing Yang and Li Liu

J of Applied Polymer Sci, 2024, 141
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Recent Progress on Sustainable 2,5-Furandicarboxylate-Based Polyesters: Properties and Applications

Mohammad Raza Miah, Yunxiao Dong, Jinggang Wang and Jin Zhu

ACS Sustainable Chem. Eng., 2024, 12, 2927
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Fluctuating Behavior and Ligand-Dependent Reactivity of Isocyanates with Bis(pentafulvene)titanium Complexes

Marcel Eilers, Tobias Bötel, Kevin Schwitalla, Marc Schmidtmann and Rüdiger Beckhaus

Inorg. Chem., 2025, 64, 12990
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Biodegradable and biocompatible nonisocyanate polyurethanes synthesized from bio-derived precursors

Bantumelli Prasannatha, Billa Narasimha Rao, Kunduru Konda Reddy, Chiranjeevi Padala, Bramanandam Manavathi and Tushar Jana

Polymer, 2024, 309, 127446
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Beyond isocyanates: Advances in non-isocyanate polyurethane chemistry and applications

Mayankkumar L. Chaudhary, Rutu Patel and Ram K. Gupta

Polymer, 2025, 332, 128553
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Synthesis of organic-solvent-soluble cellulose and preparation of fluorescent polyurethanes for the detection and removal of Hg+ ions

Lin Yun, Jiao He and Xinjian Cheng

International Journal of Biological Macromolecules, 2024, 254, 127727
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Thermoplastic polyurethane/POSS nanohybrids: Synthesis, morphology, and biological properties

Jan Ozimek, Katarzyna Malarz, Anna Mrozek‐Wilczkiewicz, Edyta Hebda and Krzysztof Pielichowski

J Biomed Mater Res, 2024, 112
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Leveraging biogenic resources to achieve global plastic decarbonization by 2050

Elisabeth Van Roijen and Sabbie A. Miller

Nat Commun, 2025, 16
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Design and Development of Sustainable Polyurethane Foam: A Proof‐of‐Concept as Customizable Packaging for Cultural Heritage Applications

Annachiara Pascarella, Federica Recupido, Giuseppe Cesare Lama, Luigi Sorrentino, Assunta Campanile, Barbara Liguori, Mathéo Berthet, Gennaro Rollo, Marino Lavorgna and Letizia Verdolotti

Adv Eng Mater, 2024, 26
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Ru(III)-PhI(OAc)2─A Combination for Generation of Isocyanate Intermediate from Benzimidate through a Rearrangement: Synthesis of Unsymmetrical Urea, Carbamate, and Chiral Analogues

Shobhon Aich, Mriganka Saha, Debasish Ghosh, Sabir Ali Molla, Ankan Kumar Sarkar, Debanjana Bag, Rajjakfur Rahaman, Saikat Khamarui and Dilip K. Maiti

Org. Lett., 2024, 26, 10970
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Foam-to-adhesive recycling of self-blown non-isocyanate polyurethane foams facilitated by integration of disulfide exchangeable bonds and moisture

Víctor D. Lechuga-Islas, Emeline Gillissen, Maxime Bourguignon, Bruno Grignard and Christophe Detrembleur

Chemical Engineering Journal, 2025, 516, 163998
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Revival of Polyester-Based Polyurethane Technology: High-Yield Monomer Recovery Using Scalable, Basic Chemical Processes

Patrick Schara, Tankut Türel, Berend Eling and Željko Tomović

ACS Sustainable Chem. Eng., 2025, 13, 4526
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Bentonite as eco-friendly natural mineral support for Pd/CoFe2O4 catalyst applied in toluene diamine synthesis

Alpár F. Hatvani-Nagy, Viktória Hajdu, Ágnes Mária Ilosvai, Gábor Muránszky, Emőke Sikora, Ferenc Kristály, Lajos Daróczi, Béla Viskolcz, Béla Fiser and László Vanyorek

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State-of-the-Art Polyurea Coatings: Synthesis Aspects, Structure–Properties Relationship, and Nanocomposites for Ballistic Protection Applications

Gabriela Toader, Aurel Diacon, Sorin Mircea Axinte, Alexandra Mocanu and Edina Rusen

Polymers, 2024, 16, 454
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Reducing High-Molecular-Weight Oligomers in Biobased Pentamethylene Diisocyanate Trimers

Yue Yang, Qixu Hu, Feng He, Peng Ma, Ganlu Li, Hui Li and Kequan Chen

Ind. Eng. Chem. Res., 2024, 63, 10482
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Thermoplastic Polyurethane/Polylactic Acid Blend Foams Loaded With Curcuma longa L. and Hypericum perforatum Extracts Towards Wound Dressing Applications

Aleksandra Bužarovska, Jasmina Petreska Stanoeva, Predrag Karamanolevski, Andreea Daniela Popa, Sorina Dinescu and Luc Avérous

J of Applied Polymer Sci, 2025, 142
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Amphiphilic Polyurethane with Cluster-Induced Emission for Multichannel Bioimaging in Living Cell Systems

Nan Jiang, Ke-Xin Li, Jia-Jun Wang, You-Liang Zhu, Chang-Yi Zhu, Yan-Hong Xu and Martin R. Bryce

ACS Macro Lett., 2024, 13, 52
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Advances in the degradation and recycling of polyurethanes: biodegradation strategies, MALDI applications, and environmental implications

Joanna Drzeżdżon and Janusz Datta

Waste Management, 2025, 198, 21
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Bio‐Based Elastomers: Design, Properties, and Biomedical Applications

Qingsheng Liu, Pengfei Lou, Zhentao Sun, Daochang Li, Haijun Ji, Zhengzhuo Xu, Lei Li, Jiajia Xue, Runguo Wang, Zhao Wang and Liqun Zhang

Advanced Materials, 2025, 37
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Innovations in applications and prospects of non‐isocyanate polyurethane bioplastics

Mangal Mangal, Supriya H., Suryasarathi Bose and Tamal Banerjee

Biopolymers, 2023, 114
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Eco-friendly materials for structural insulated panels: A comprehensive review

R.N. De Zoysa, K.S. Kristombu Baduge, P.S.M. Thilakarathna, Xuemei Liu, S. Costa, U. Gunarathne, E. Cazacu and T. Braunsch

Journal of Building Engineering, 2025, 113, 114059
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Development of lightweight particleboards using epoxidized soybean oil foamable adhesive

Jie Zhang, Shupin Luo, Li Gao, Fenghao Zhang, Qiheng Tang and Wenjing Guo

Polymer Composites, 2025, 46
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Preparation, Reaction Kinetics, and Properties of Polyester Foams Using Water Produced by the Reaction as a Foaming Agent

Fabian Weitenhagen and Oliver Weichold

Polymers, 2025, 17, 1266
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Recyclable Hydrophobic Polyurethanes and Debondable Coatings Utilizing Apolar Acetal Polyols

Patrick Schara, Tankut Türel, Christos Pantazidis, Anna Maria Cristadoro, Rint P. Sijbesma and Željko Tomović

ACS Appl. Polym. Mater., 2025, 7, 6055
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Accelerated Aging on the Compression Properties of a Green Polyurethane Foam: Experimental and Numerical Analysis

Enio H. P. Da Silva, Silvio De Barros, André F. C. Vieira, Romeu R. C. Da Costa and Marcelo L. Ribeiro

Polymers, 2023, 15, 1784
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Fructose-Based Non-Isocyanate Polyurethane/Poly (Sodium Acrylate) Hydrogels: Design, Synthesis and Environmental Applications

Pooja Singh and Raminder Kaur

J Polym Environ, 2024, 32, 2897
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A concise strategy for enhancing the performance of bio-based polyurethane aerogels using melamine-modified sodium alginate via Aza-Michael addition reaction

Qingyu Liao, Huimin Ren, Jiatong Xu, Pengguang Wang, Ziyu Zhou, Yixin Wang, Baihua Yuan and Hongbin Zhang

Chemical Engineering Journal, 2024, 500, 157361
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Bio-based polyurethane coatings for controlled-release phosphorus fertilizers: Synthesis, characterization and effect on P use efficiency

Eduardo Lopes Cancellier, Fien Degryse, Rodrigo C. da Silva, Roslyn Baird, Douglas Guelfi and Mike J. McLaughlin

Science of The Total Environment, 2025, 1000, 180403
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Recent developments in the sustainability of the production of polyurethane foams from polyols based on the first- to the fourth-generation of biomass feedstock

Ugis Cabulis and Aiga Ivdre

Current Opinion in Green and Sustainable Chemistry, 2023, 44, 100866
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Nonisocyanate Polyurethanes Originated from Biobased Isosorbide with Good Combined Properties

Danqing Song, Jin He, Qiqi Xie, Xuedong Lv, Yi Liu and Liuchun Zheng

ACS Appl. Polym. Mater., 2024, 6, 8133
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Fast-curing bio-based thermoset foams produced via the Michael 1,4-addition using fatty acid-based acetoacetate and acrylate

Ralfs Pomilovskis, Eliza Kaulina, Arnis Abolins, Inese Mierina, Ivo Heinmaa, Vitalijs Rjabovs, Anda Fridrihsone and Mikelis Kirpluks

European Polymer Journal, 2024, 210, 112968
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Atom-Economic Synthesis of Phosphorus-Containing Biobased Aromatic Diol for Flame-Retardant Robust Polyurethane

Kai Ma, Qin Chen, Yunqi Li, Yang You, Guanglong Zou and Haibo Xie

ACS Appl. Polym. Mater., 2024, 6, 4830
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Bio-Based Polyurethane Foams: Feedstocks, Synthesis, and Applications

Marta Santos, Marcos Mariz, Igor Tiago, Susana Alarico and Paula Ferreira

Biomolecules, 2025, 15, 680
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Sustainable synthesis of waste soybean oil-based non-isocyanate polyurethane elastomers and foams

Chinh Hoang Tran, Ji-Hwan Park, Soo-Young Lee, Byeol Han, Won Seok Jae, Han Su Lee, Hyun-jong Paik and Il Kim

Polymer, 2025, 323, 128217
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A Vegetable-Oil-Based Polyurethane Coating for Controlled Nutrient Release: A Review

Lyu Yao, Azizah Baharum, Lih Jiun Yu, Zibo Yan and Khairiah Haji Badri

Coatings, 2025, 15, 665
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Non-isocyanate Polythiourethane Network from Biowaste: Achieving Circularity via Multidimensional Chemical Recycling with Valuable Small-Molecule Recovery and Reprocessability by Understanding the Dynamic Chemistry

Yixuan Chen, Nicholas Mielke, Nathan S. Purwanto, Boran Chen, Christos D. Malliakas and John M. Torkelson

Macromolecules, 2024, 57, 490
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Closed-Loop Recycling and Upcycling of Fully Biobased Poly(thiourethane) Covalent Adaptable Networks

Seulchan Lee, Jihong Lyu, Anwoo Jeong, Minsol Jung, Ju Hyeong Kang, Hyocheol Jung, Young Il Park, Ji-Eun Jeong and Jin Chul Kim

ACS Sustainable Chem. Eng., 2024, 12, 12386
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The current progress of tandem chemical and biological plastic upcycling

Yifeng Hu, Yuxin Tian, Chenghao Zou and Tae Seok Moon

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Renewable Terephthalates and Aromatic Diisocyanates from Galactose

Matthew W. Halloran, Roxanne Naumann, Aanchal Jaisingh, Nathan A. Romero and Michael D. Burkart

Angew Chem Int Ed, 2025, 64
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Renewable Terephthalates and Aromatic Diisocyanates from Galactose

Matthew W. Halloran, Roxanne Naumann, Aanchal Jaisingh, Nathan A. Romero and Michael D. Burkart

Angewandte Chemie, 2025, 137
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Chemical recycling of nitrogen containing polymers: processes and industrial prospects

Sofie Houben, Marta Mestre Membrado, Lander Van Belleghem, Ion Olazabal, Niels Van Velthoven, Karolien Vanbroekhoven, Haritz Sardon, Dirk De Vos, Elias Feghali and Kathy Elst

Progress in Polymer Science, 2025, 168, 102002
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The influence of bio-based monomers on the structure and thermal properties of polyurethanes

Joanna Brzoska, Janusz Datta, Rafał Konefał, Václav Pokorný and Hynek Beneš

Sci Rep, 2024, 14
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How biomimetic nanofibers advance the realm of cutaneous wound management: The state-of-the-art and future prospects

Niloofar Eslahi, Foad Soleimani, Roya Lotfi, Fatemeh Mohandes, Abdolreza Simchi and Mehdi Razavi

Progress in Materials Science, 2024, 145, 101293
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Copper‐Mediated Synthesis of N‐Aryl‐Oxamic Acids

Margaux Badufle, Frédéric Robert and Yannick Landais

Chemistry A European J, 2024, 30
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Green polyurethanes from bio-based building blocks: Recent advances and applications

Filippo Campana, Giulia Brufani, Francesco Mauriello, Rafael Luque and Luigi Vaccaro

Green Synthesis and Catalysis, 2025, 6, 217
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Biodegradable Polyurethane Derived from Hydroxylated Polylactide with Superior Mechanical Properties

Xueqin Li, Yanyan Lin, Cengceng Zhao, Na Meng, Ying Bai, Xianfeng Wang, Jianyong Yu and Bin Ding

Polymers, 2024, 16, 1809
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Biodegradable and biocompatible non-isocyanate polyurethane derived from recycled polycarbonate e-waste for skin tissue engineering

Debleena Ghosh, Sumedha Das and Kishor Sarkar

European Polymer Journal, 2025, 237, 114177
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Variation of Aliphatic Diisocyanates in Bio-Based TPUs

Bhausaheb S. Rajput, Aaron Forman, Matthew W. Halloran, Thien An Phung Hai, Gordon B. Scofield and Michael D. Burkart

Macromolecules, 2023, 56, 8813
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Nonleaching Biocidal N-Halamine-Functionalized Polyamine-, Guanidine-, and Hydantoin-Based Coatings

Lev Bromberg, Beatriz Magariños, Angel Concheiro, T. Alan Hatton and Carmen Alvarez-Lorenzo

Ind. Eng. Chem. Res., 2024, 63, 6268
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Upcycling of medium-density fiberboard and polyurethane foam wastes into novel composite materials

Aleksander Hejna, Mateusz Barczewski, Joanna Aniśko, Adam Piasecki, Roman Barczewski, Paulina Kosmela, Jacek Andrzejewski and Marek Szostak

Resources, Conservation & Recycling Advances, 2025, 25, 200244
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Synthesis and chemical recycling investigations of polythioureas

Rafael N.L. de Menezes, Olga Gordivska, Tran Tam Nguyen, Niklas Warlin, Nicola Rehnberg and Baozhong Zhang

Reactive and Functional Polymers, 2024, 205, 106062
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Biobased Flame-Retardant Polylactic Acid Foams through Lignin-Based Nanocarriers Encapsulating Deoxyribonucleic Acid

Hugo Ridard, Joost Duvigneau, Thomas Mayer-Gall, Wael Ali and Frederik R. Wurm

ACS Sustainable Chem. Eng., 2024, 12, 14866
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