Issue 15, 2021
From the journal:

Journal of Materials Chemistry C

Single crystal to single crystal transformation of spin-crossover coordination polymers from 3D frameworks to 2D layers†

Yu Gong,‡a   Wang-Kang Han,‡a   Hui-Shu Lu,a   Qing-Tao Hu,a   Huan Tu,a   Pei-Ni Li,a   Xiaodong Yan ORCID logo a  and  Zhi-Guo Gu ORCID logo *ab  

* Corresponding authors

a The Key Laboratory of Synthetic and Biological Colloids, Ministry of Education, School of Chemical and Material Engineering, Jiangnan University, Wuxi 214122, P. R. China
E-mail: zhiguogu@jiangnan.edu.cn

b International Joint Research Center for Photoresponsive Molecules and Materials, School of Chemical and Material Engineering, Jiangnan University, Wuxi 214122, P. R. China

Abstract

A ligand exchange induced single crystal to single crystal (SCSC) transformation from 3D Hofmann-type frameworks [Fe(ep)M(CN)4] (ep = ethylpyrazine; M = Pt, Pd) to 2D layer networks [Fe(mp)2M(CN)4] (mp = methoxypyrazine) was observed. Interestingly, the different pillar–ligands showed a significant influence on the structural assembly and spin-crossover properties.

Graphical abstract: Single crystal to single crystal transformation of spin-crossover coordination polymers from 3D frameworks to 2D layers

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/D1TC00470K
Article type
Communication
Submitted
30 جنؤری 2021
Accepted
18 مارٕچ 2021
First published
19 مارٕچ 2021

J. Mater. Chem. C, 2021,9, 5082-5087

Permissions

Request permissions

Single crystal to single crystal transformation of spin-crossover coordination polymers from 3D frameworks to 2D layers

Y. Gong, W. Han, H. Lu, Q. Hu, H. Tu, P. Li, X. Yan and Z. Gu, J. Mater. Chem. C, 2021, 9, 5082 DOI: 10.1039/D1TC00470K

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements