Issue 74, 2020

[Cp*RuPb11]3− and [Cu@Cp*RuPb11]2−: centered and non-centered transition-metal substituted zintl icosahedra

Abstract

Cluster anions [Cp*RuPb11]3− (1) and [Cu@Cp*RuPb11]2− (2) represent the first vertex-substituted zintl icosahedra and 1 is the first non-centered zintl icosahedron isolated in the condensed phase. Complexes 1 and 2 are both 12-vertex, 26-electron closo-clusters with C5v point symmetry and are static on the 207Pb NMR time scale in solution.

Graphical abstract: [Cp*RuPb11]3− and [Cu@Cp*RuPb11]2−: centered and non-centered transition-metal substituted zintl icosahedra

Supplementary files

Article information

Article type
Communication
Submitted
24 جوٗن 2020
Accepted
06 اگست 2020
First published
06 اگست 2020

Chem. Commun., 2020,56, 10859-10862

Author version available

[Cp*RuPb11]3− and [Cu@Cp*RuPb11]2−: centered and non-centered transition-metal substituted zintl icosahedra

A. Li, Y. Wang, P. Y. Zavalij, F. Chen, A. Muñoz-Castro and B. W. Eichhorn, Chem. Commun., 2020, 56, 10859 DOI: 10.1039/D0CC03656K

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements