Issue 27, 2019

Unusual temperature-sensitive excimer fluorescence from discrete π–π dimer stacking of anthracene in a crystal

Abstract

Herein, an unusual blue shift in excimer fluorescence with increasing temperature was observed from a crystal with a discrete π–π anthracene dimer, originating from the more temperature-sensitive intermolecular geometry of the π–π dimer (e.g., π–π distance) compared to the intramolecular geometry of the monomer, which is confirmed by temperature-dependent single-crystal X-ray diffraction (XRD) measurements.

Graphical abstract: Unusual temperature-sensitive excimer fluorescence from discrete π–π dimer stacking of anthracene in a crystal

Supplementary files

Article information

Article type
Communication
Submitted
10 میٔ 2019
Accepted
17 جوٗن 2019
First published
17 جوٗن 2019

Phys. Chem. Chem. Phys., 2019,21, 14511-14515

Unusual temperature-sensitive excimer fluorescence from discrete π–π dimer stacking of anthracene in a crystal

Y. Shen, H. Liu, J. Cao, S. Zhang, W. Li and B. Yang, Phys. Chem. Chem. Phys., 2019, 21, 14511 DOI: 10.1039/C9CP02656H

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements