A simple and general procedure for the preparation of Diels–Alder adducts of perfluorinated thioketones and various dienes is reported. The corresponding Diels–Alder adducts were prepared in 30–78% yield under mild conditions via a reaction of a mixture of fluoroolefins, sulfur, diene and CsF as a catalyst.
V. Petrov, A. A. Marchione and R. Dooley, Chem. Commun., 2018, 54, 9298 DOI: 10.1039/C8CC05075A
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