Issue 11, 2017

Universal selection rule for surfactants used in miniemulsion processes for eco-friendly and high performance polymer semiconductors

Abstract

Commercial interest in the environmentally friendly processing of polymer semiconductors is on the rise. To reduce noxious solvent use and to realize water-borne colloids of polymer semiconductors, we developed a universal and eco-friendly miniemulsion process to satisfy four essential criteria: (1) efficient emulsification for synthesizing small and uniform polymer semiconductor particles, (2) efficient coalescence of particles to yield high quality thin films with low roughness and high fill-factors, (3) efficient removal of residual surfactants, and (4) high ordering of polymers within particles. We screened various surfactants to find conditions that satisfied the suggested selection rules regardless of the charge polarity and molecular structure of the polymer semiconductor. Our universal method can be applied to first-generation polythiophene derivatives as well as to the latest p-type, n-type and ambipolar polymers with planar backbones and high charge carrier mobility. Using these results, we fabricated for the first time a high-performance complementary inverter and a photodiode using water as a processing solvent.

Graphical abstract: Universal selection rule for surfactants used in miniemulsion processes for eco-friendly and high performance polymer semiconductors

Supplementary files

Article information

Article type
Paper
Submitted
13 جوٗلایی 2017
Accepted
31 اگست 2017
First published
31 اگست 2017

Energy Environ. Sci., 2017,10, 2324-2333

Universal selection rule for surfactants used in miniemulsion processes for eco-friendly and high performance polymer semiconductors

J. Cho, S. Yoon, K. Min Sim, Y. Jin Jeong, C. Eon Park, S. Kwon, Y. Kim and D. S. Chung, Energy Environ. Sci., 2017, 10, 2324 DOI: 10.1039/C7EE01943B

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements