Issue 45, 2013
From the journal:

CrystEngComm

A mesoporous lanthanide–organic framework constructed from a dendritic hexacarboxylate with cages of 2.4 nm†

Yabing He,*a   Hiroyasu Furukawa,b   Chuande Wu,c   Michael O'Keeffed  and  Banglin Chen*e  

* Corresponding authors

a College of Chemistry and Life Sciences, Zhejiang Normal University, Jinhua 321004, China
E-mail: heyabing@gmail.com

b Department of Chemistry, University of California, Materials Sciences Division, Lawrence Berkeley National Laboratory, Berkeley, California 94720, USA

c Department of Chemistry, Zhejiang University, Hangzhou 310027, China

d Department of Chemistry and Biochemistry, Arizona State University, Tempe, Arizona 85287, USA

e Department of Chemistry, University of Texas at San Antonio, One UTSA Circle, San Antonio, Texas 78249-0698, USA
E-mail: banglin.chen@utsa.edu
Fax: +1-210-458-7428

Abstract

Solvothermal reaction of a dendritic hexacarboxylic acid with Tb(NO3)3·6H2O afforded a mesoporous lanthanide–organic framework (UTSA-61) whose single-crystal X-ray structure was characterized to have octahedral cages of 2.4 nm in diameter. This mesoporous MOF not only exhibits novel hey topology, but also maintains permanent porosity as shown in its N2, H2, CO2 and CH4 gas sorption isotherms.

Graphical abstract: A mesoporous lanthanide–organic framework constructed from a dendritic hexacarboxylate with cages of 2.4 nm

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/C3CE41062E
Article type
Communication
Submitted
08 جوٗن 2013
Accepted
29 جوٗلایی 2013
First published
31 جوٗلایی 2013

CrystEngComm, 2013,15, 9328-9331

Permissions

Request permissions

A mesoporous lanthanide–organic framework constructed from a dendritic hexacarboxylate with cages of 2.4 nm

Y. He, H. Furukawa, C. Wu, M. O'Keeffe and B. Chen, CrystEngComm, 2013, 15, 9328 DOI: 10.1039/C3CE41062E

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements