Issue 83, 2012
From the journal:

Chemical Communications

Control of framework interpenetration for in situ modified hydroxyl functionalised IRMOFs†‡

Damien Rankine,a   Antonio Avellaneda,a   Matthew R. Hill,b   Christian J. Doonan*a  and  Christopher J. Sumby*a  

* Corresponding authors

a School of Chemistry & Physics, The University of Adelaide, Adelaide, Australia
E-mail: christian.doonan@adelaide.edu.au, christopher.sumby@adelaide.edu.au
Fax: +61 8 8303 4358
Tel: +61 8 8303 5770

b CSIRO Materials Science and Engineering, Clayton, Australia

Abstract

By intimate control of reaction conditions, phase-pure crystalline porous metal–organic framework materials [Zn4O(L)3] with interpenetrated and non-interpenetrated structures can be synthesised. Under certain conditions, these reactions occur with concomitant deprotection of masked alcohols located on the organic links which yield accessible ‘metal-binding’ functional groups within the frameworks.

Graphical abstract: Control of framework interpenetration for in situ modified hydroxyl functionalised IRMOFs

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Article information

DOI
https://doi.org/10.1039/C2CC35565E
Article type
Communication
Submitted
01 اگست 2012
Accepted
31 اگست 2012
First published
31 اگست 2012

Chem. Commun., 2012,48, 10328-10330

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Control of framework interpenetration for in situ modified hydroxyl functionalised IRMOFs

D. Rankine, A. Avellaneda, M. R. Hill, C. J. Doonan and C. J. Sumby, Chem. Commun., 2012, 48, 10328 DOI: 10.1039/C2CC35565E

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