Four-Step Electron Transfer Coupled Spin Transition in a Cyano-bridged [Fe2Co2] Square Complex
Abstract
The design of molecular functional materials with multi-step magnetic transitions has attracted considerable attention. However, the development of such materials is still infrequent and challenging. Here, a cyano-bridged square Prussian blue complex that exhibits a thermally induced four-step electron transfer coupled spin transition (ETCST) is reported. The magnetic and spectroscopic analyses confirm this multi-step transition. Variable-temperature infrared spectrum suggested the electronic structures in each phase and proposed a four-step transition model.
- This article is part of the themed collection: Recent progress and perspectives on spin transition compounds