Energy level regulation of anions via hydrogen bond effects to construct a stable solid electrolyte interface for a high-stability lithium metal anode

Abstract

An intermolecular hydrogen bond between 2,5-dihydroxyterephthalic acid and the anions in the Li⁺ solvation shell is constructed to promote the formation of a LiF-rich SEI on a metallic Li electrode. Li metal batteries with improved cyclability (140 cycles under an N/P ratio of 4.9) and high capacity retention (90%) are eventually obtained.