Issue 15, 2022

Difunctionalization of unactivated olefins via selective electrochemical chlorosulfuration or chlorosulfoxidation

Abstract

Direct difunctionalization of olefins—which are the most commonly used compounds in organic synthesis—is a powerful tool for rapid formation of structurally complex building blocks from readily available starting materials. However, difunctionalization of unactivated olefins remains a formidable challenge. Herein, we describe a green, cost-effective, and eco-friendly electrochemical protocol for selective chlorosulfuration or chlorosulfoxidation of unactivated alkenes. This electrochemical method creates the potential possibility for the preparation of high-value-added products in a more sustainable and greener manner.

Graphical abstract: Difunctionalization of unactivated olefins via selective electrochemical chlorosulfuration or chlorosulfoxidation

Supplementary files

Article information

Article type
Communication
Submitted
07 جوٗن 2022
Accepted
12 جوٗلایی 2022
First published
13 جوٗلایی 2022

Green Chem., 2022,24, 5760-5763

Difunctionalization of unactivated olefins via selective electrochemical chlorosulfuration or chlorosulfoxidation

P. Zhou, K. Niu, H. Song, Y. Liu and Q. Wang, Green Chem., 2022, 24, 5760 DOI: 10.1039/D2GC02134J

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements