Issue 19, 2021

Structural determination of a metastable Ag27 nanocluster and its transformations into Ag8 and Ag29 nanoclusters

Abstract

Research on nanocluster transformation has generally focused on stable nanoclusters, while analysis of the structural evolutions of metastable nanoclusters just began to receive attention recently. Herein, we report the structural determination of a metastable Ag27H11(SPhMe2)12(DPPM)6 nanocluster and its spontaneous transformation into a size-reduction Ag8(SPhMe2)8(DPPM)1 nanocluster as well as ligand-exchange-triggered transformation into a size-growth Ag29(SSR)12(DPPM)4 nanocluster. The new structure of Ag27 and its structural transformations hopefully provide some implication to the in-depth understanding of metastable nanoclusters.

Graphical abstract: Structural determination of a metastable Ag27 nanocluster and its transformations into Ag8 and Ag29 nanoclusters

Supplementary files

Article information

Article type
Research Article
Submitted
03 جوٗن 2021
Accepted
02 اگست 2021
First published
03 اگست 2021

Inorg. Chem. Front., 2021,8, 4407-4414

Structural determination of a metastable Ag27 nanocluster and its transformations into Ag8 and Ag29 nanoclusters

C. Zhu, T. Duan, H. Li, X. Wei, X. Kang, Y. Pei and M. Zhu, Inorg. Chem. Front., 2021, 8, 4407 DOI: 10.1039/D1QI00684C

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements