Issue 4, 2020

Emerging investigator series: capacitive deionization for selective removal of nitrate and perchlorate: impacts of ion selectivity and operating constraints on treatment costs

Abstract

Treating toxic monovalent anions such as NO3 or ClO4 in drinking water remains challenging due to the high capital and environmental costs associated with common technologies such as reverse osmosis or ion exchange. Capacitive deionization (CDI) is a promising technology for selective ion removal due to high reported ion selectivity for these two contaminants. However, the impacts of ion selectivity and influent water characteristics on CDI life cycle cost have not been considered. In this study we investigate the impact of ion selectivity on CDI system cost with a parameterized process model and technoeconomic analysis framework. Simulations indicate millimolar concentration contaminants such as nitrate can be removed at costs in the range of $0.01–0.30 per m3 at reported selectivity coefficient ranges (S = 6–10). Since perchlorate removal involves micromolar scale concentration changes, higher selectivity values than reported in literature (S > 10 vs. S = 4–6.5) are required for comparable treatment costs. To contextualize simulated results for CDI treatment of NO3, CDI unit operations were sized and costed for three case studies based on existing treatment facilities in Israel, Spain, and the United States, showing that achieving a nitrate selectivity of 10 could reduce life cycle treatment costs below $0.2 per m3.

Graphical abstract: Emerging investigator series: capacitive deionization for selective removal of nitrate and perchlorate: impacts of ion selectivity and operating constraints on treatment costs

Supplementary files

Article information

Article type
Paper
Submitted
13 دسمبر 2019
Accepted
16 جنؤری 2020
First published
17 جنؤری 2020

Environ. Sci.: Water Res. Technol., 2020,6, 925-934

Author version available

Emerging investigator series: capacitive deionization for selective removal of nitrate and perchlorate: impacts of ion selectivity and operating constraints on treatment costs

S. Hand and R. D. Cusick, Environ. Sci.: Water Res. Technol., 2020, 6, 925 DOI: 10.1039/C9EW01105F

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements