Issue 43, 2020

The synthesis and versatile reducing power of low-valent uranium complexes

Abstract

This Perspective provides a detailed overview of the chemistry of low-valent (di- and trivalent) uranium. The reactivity of uranium(II) and uranium(III) complexes is discussed both to illustrate the general types of reactions that might be expected and to highlight the many unusual modes of reactivity observed with this element. A particular emphasis is given to redox reactions with uranium(III) species, including reduction of small molecules, multi-electron reductions involving redox-active ligands, and formation of uranium–ligand multiple bonds. In addition, redox-neutral adduct formation with uranium(III) complexes as well as the current state of the young field of uranium(II) redox chemistry are also covered. Synthetic protocols to prepare a wide range of low-valent compounds are presented.

Graphical abstract: The synthesis and versatile reducing power of low-valent uranium complexes

Article information

Article type
Perspective
Submitted
08 ستمبر 2020
Accepted
05 اکتوٗبر 2020
First published
12 اکتوٗبر 2020

Dalton Trans., 2020,49, 15124-15138

Author version available

The synthesis and versatile reducing power of low-valent uranium complexes

M. A. Boreen and J. Arnold, Dalton Trans., 2020, 49, 15124 DOI: 10.1039/D0DT03151H

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements