Issue 12, 2019

Distinct photophysical properties in atom-precise silver and copper nanocluster analogues

Abstract

The synthesis of atom-precise analogues of homometallic nanoclusters remains a great challenge. Herein we report the first pair of atom-precise copper/silver-thiolate halide cluster analogues, namely [Cu17/Ag17I3S(C2B10H10S2)6(CH3CN)11] (Cu17 and Ag17), obtained by bottom-up self-assembly and complete-metal-exchange-induced cluster-to-cluster transformation, respectively. The differences in optical absorption and emission of these analogues were fully elucidated by experimental and theoretical methods.

Graphical abstract: Distinct photophysical properties in atom-precise silver and copper nanocluster analogues

Supplementary files

Article information

Article type
Communication
Submitted
01 فرؤری 2019
Accepted
28 فرؤری 2019
First published
01 مارٕچ 2019

Nanoscale, 2019,11, 5151-5157

Distinct photophysical properties in atom-precise silver and copper nanocluster analogues

Y. Li, Z. Wang, X. Ma, P. Luo, C. Du and S. Zang, Nanoscale, 2019, 11, 5151 DOI: 10.1039/C9NR01058K

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements