Two-electron oxidation of a homoleptic U(III) guanidinate complex by diphenyldiazomethane

Nicholas S. Settineri; Angela A. Shiau; John Arnold

doi:10.1039/C8CC06514D

You do not have JavaScript enabled. Please enable JavaScript to access the full features of the site or access our non-JavaScript page.

Two-electron oxidation of a homoleptic U(iii) guanidinate complex by diphenyldiazomethane†

Nicholas S. Settineri,

‡^ab Angela A. Shiau ‡^a and John Arnold

*^ab

Author affiliations

* Corresponding authors

^a Department of Chemistry, University of California, Berkeley, California 94720, USA
E-mail: arnold@berkeley.edu

^b Chemical Sciences Division, Lawrence Berkeley National Laboratory, Berkeley, California 94720, USA

Abstract

Reaction of the first homoleptic U(III) guanidinate complex with diphenyldiazomethane results in two-electron oxidation of U(III) to U(V) and isolation of a U(V) hydrazido complex. Corresponding U(V) imido, U(V) oxo, and U(IV) azido complexes were also synthesized for structural comparison.

This article is part of the themed collection: New molecules and materials from the f-block

Download options Please wait...

Supplementary files

Article information

DOI: https://doi.org/10.1039/C8CC06514D
Article type: Communication
Submitted: 09 اگست 2018
Accepted: 06 ستمبر 2018
First published: 12 ستمبر 2018

Download Citation

Chem. Commun., 2018,54, 10913-10916

Author version available

Download author version (PDF)

Permissions

Request permissions

Two-electron oxidation of a homoleptic U(III) guanidinate complex by diphenyldiazomethane

N. S. Settineri, A. A. Shiau and J. Arnold, Chem. Commun., 2018, 54, 10913 DOI: 10.1039/C8CC06514D

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Social activity

Fetching data from CrossRef.
This may take some time to load.

Chemical Communications

Two-electron oxidation of a homoleptic U(iii) guanidinate complex by diphenyldiazomethane†

Abstract

Supplementary files

Article information

Download Citation

Author version available

Permissions

Two-electron oxidation of a homoleptic U(III) guanidinate complex by diphenyldiazomethane

Social activity

Search articles by author

Spotlight

Advertisements