Issue 19, 2016

Stability of solution-processed MAPbI3 and FAPbI3 layers

Abstract

We provide a semi-empirical model based on in situ degradation measurements to predict the durability of hybrid perovskite materials under simulated thermal operation conditions. In the model, the degradation path of MAPbI3 layers is proved to follow an Arrhenius-type law. The predictive role is played by the activation energy combined with its pre-exponential factor. Our comparative study under moisture conditions with respect to vacuum and nitrogen treatments has assessed the occurrence of an intrinsic dynamic exchange of protons between the organic cations and the inorganic cage with a direct impact on the lattice stability, for which the presence of water molecules is not mandatory. This mutual interaction produces defects inside the material and volatile species, such as HI, CH3NH2 or MAI, with an associated experimental activation energy of 1.54 eV measured under vacuum conditions in dark. This value is comparable to that calculated by the density functional theory for defect generation in MAPbI3. In air, the action of water molecules reduces the activation energy for proton exchanges in dark to 0.96 eV. As an alternative solution to increase the material stability, we demonstrate that the substitution of methylammonium (MA+) with the formamidinium (FA+) cations inside the inorganic cage gives greater robustness to the overall lattice and extends the material durability due to a different interaction between the organic molecules and the inorganic cage. This definitely supports the use of FAPbI3 in applications, provided its structure can be stabilized in the dark phase at room temperature.

Graphical abstract: Stability of solution-processed MAPbI3 and FAPbI3 layers

Supplementary files

Article information

Article type
Paper
Submitted
01 فرؤری 2016
Accepted
11 اپریل 2016
First published
15 اپریل 2016

Phys. Chem. Chem. Phys., 2016,18, 13413-13422

Stability of solution-processed MAPbI3 and FAPbI3 layers

E. Smecca, Y. Numata, I. Deretzis, G. Pellegrino, S. Boninelli, T. Miyasaka, A. La Magna and A. Alberti, Phys. Chem. Chem. Phys., 2016, 18, 13413 DOI: 10.1039/C6CP00721J

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements