Issue 1, 2015

DNA based multi-copper ions assembly using combined pyrazole and salen ligandosides

Abstract

The DNA structure is an ideal building block for the construction of functional nano-objects. In this direction, metal coordinating base pairs (ligandosides) are an appealing tool for the future specific functionalization of such nano-objects. We present here a study, in which we combine the metal ion coordinating pyrazole ligandoside with the interstrand crosslinking salen ligandoside system. We show that both ligandosides, when combined, are able to create stable multi-copper ion complexing DNA double helix structures in a cooperative fashion.

Graphical abstract: DNA based multi-copper ions assembly using combined pyrazole and salen ligandosides

Supplementary files

Article information

Article type
Edge Article
Submitted
28 میٔ 2014
Accepted
05 اگست 2014
First published
11 اگست 2014
This article is Open Access

All publication charges for this article have been paid for by the Royal Society of Chemistry
Creative Commons BY license

Chem. Sci., 2015,6, 632-638

Author version available

DNA based multi-copper ions assembly using combined pyrazole and salen ligandosides

M. Su, M. Tomás-Gamasa and T. Carell, Chem. Sci., 2015, 6, 632 DOI: 10.1039/C4SC01567C

This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. You can use material from this article in other publications without requesting further permissions from the RSC, provided that the correct acknowledgement is given.

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