Issue 39, 2013
From the journal:

Chemical Communications

Aerobic oxidative N-dealkylation of tertiary amines in aqueous solution catalyzed by rhodium porphyrins†‡

Zhen Ling,a   Lin Yun,a   Lianghui Liu,a   Bing Wua  and  Xuefeng Fu*a  

* Corresponding authors

a Beijing National Laboratory for Molecular Sciences, State Key Lab of Rare Earth Materials Chemistry and Applications, Peking University, Beijing, China
E-mail: fuxf@pku.edu.cn
Fax: +86 10 6275 1708
Tel: +86 10 6275 6035

Abstract

Aerobic oxidative N-dealkylation of a variety of aliphatic tertiary amines and anilines catalyzed by rhodium(III) tetra (p-sulfonatophenyl) porphyrin ((TSPP)RhIII) is achieved in aqueous solution using dioxygen as the sole oxidant.

Graphical abstract: Aerobic oxidative N-dealkylation of tertiary amines in aqueous solution catalyzed by rhodium porphyrins

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Article information

DOI
https://doi.org/10.1039/C2CC37263K
Article type
Communication
Submitted
04 اکتوٗبر 2012
Accepted
26 نومبر 2012
First published
26 نومبر 2012

Chem. Commun., 2013,49, 4214-4216

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Aerobic oxidative N-dealkylation of tertiary amines in aqueous solution catalyzed by rhodium porphyrins

Z. Ling, L. Yun, L. Liu, B. Wu and X. Fu, Chem. Commun., 2013, 49, 4214 DOI: 10.1039/C2CC37263K

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