Issue 3, 2009
From the journal:

Soft Matter

Covalent and orthogonal multi-functionalization of terpolymers

Si Kyung Yangab  and  Marcus Weck*b  

* Corresponding authors

a School of Chemistry and Biochemistry, Georgia Institute of Technology, Atlanta, GA, USA

b Department of Chemistry and Molecular Design Institute, New York University, New York, NY, USA
E-mail: marcus.weck@nyu.edu
Fax: +212 995 4895
Tel: +212 992 7968

Abstract

Random poly(norbornene)-based terpolymers containing azide, ketone and maleimide functionalities along the side-chain were synthesized using ring-opening metathesis polymerization. Subsequent side-chain functionalizations were carried out using three distinct reactions: maleimide–thiol coupling, 1,3-dipolar cycloaddition, and hydrazone formation. All investigated functionalization transformations proceed with high fidelity and absolute selectivity under mild reaction conditions.

Graphical abstract: Covalent and orthogonal multi-functionalization of terpolymers

About
Cited by
Related
Download options Please wait...

Article information

DOI
https://doi.org/10.1039/B813675K
Article type
Paper
Submitted
06 اگست 2008
Accepted
16 اکتوٗبر 2008
First published
21 نومبر 2008

Soft Matter, 2009,5, 582-585

Permissions

Request permissions

Covalent and orthogonal multi-functionalization of terpolymers

S. K. Yang and M. Weck, Soft Matter, 2009, 5, 582 DOI: 10.1039/B813675K

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements