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Abstract | Cited by

Yellow crystals of monomeric structure [Zn(bpdh)2(H2O)4](NO3)2·2bpdh (1) convert on heating at ca. 160 °C under grinding and mixing with KSCN or NaN3 to white and orange 1D coordination polymers, [Zn(µ-bpdh)2(NCS)2]n (2) and [Zn(µ-bpdh)2(N3)2]n (3), respectively. In the crystal lattice, the coordination number of Zn(II) does not change with the removal of four water molecules and forms a new type of Zn⋯Nbpdh and Zn⋯NNCS/N3.

Graphical abstract: Solid state crystal-to-crystal transformation from a monomeric structure to 1-D coordination polymers on anion exchange,

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