Issue 35, 2020

Triphosphenium salts: air-stable precursors for phosphorus(i) chemistry

Abstract

The chemistry of low-coordinate phosphorus-containing species is an area of intense interest in modern main group chemistry. While typical routes for accessing such species include pyrophoric phosphorus-centered precursors or harsh reducing agents, triphosphenium cations represent a more convenient and safer alternative. This Perspective summarizes the use of air- and moisture-stable triphosphenium salts of [dppeP]+ as a source of P+ ions for the generation of a variety of new and/or useful low-coordinate phosphorus-containing species. These range from phosphorus-rich oligomers to phosphamethine cyanine dyes. Special emphasis is placed on the electronic structure of the newly generated species as well as their subsequent reactivity.

Graphical abstract: Triphosphenium salts: air-stable precursors for phosphorus(i) chemistry

Article information

Article type
Perspective
Submitted
22 جوٗن 2020
Accepted
03 اگست 2020
First published
04 اگست 2020

Dalton Trans., 2020,49, 12115-12127

Triphosphenium salts: air-stable precursors for phosphorus(I) chemistry

E. M. Dionisi, J. F. Binder, J. H. W. LaFortune and C. L. B. Macdonald, Dalton Trans., 2020, 49, 12115 DOI: 10.1039/D0DT02219E

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements