Issue 45, 2013
From the journal:

Dalton Transactions

Palladium- or proton-induced submicro spherical aggregation of macrocyclic amphiphiles in aqueous solution†

Shohei Tashiro,a   Ryou Kubota,a   Minori Kawagoea  and  Mitsuhiko Shionoya*a  

* Corresponding authors

a Department of Chemistry, Graduate School of Science, The University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, Tokyo 113-0033, Japan
E-mail: shionoya@chem.s.u-tokyo.ac.jp
Fax: +81 3 5841 8061
Tel: +81 3 5841 8061

Abstract

Synthetic amphiphiles have been found to self-assemble into a variety of structures such as micelles, vesicles, cylinders and lamellae in aqueous media over many length scales. We report herein cation-induced aggregation of hexaaza-cyclophanes in water. Pd2+- or proton-induced formation of submicro spherical aggregates was observed by several spectroscopic and microscopic methods.

Graphical abstract: Palladium- or proton-induced submicro spherical aggregation of macrocyclic amphiphiles in aqueous solution

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Article information

DOI
https://doi.org/10.1039/C3DT51827B
Article type
Communication
Submitted
07 Jul 2013
Accepted
12 Aug 2013
First published
12 Aug 2013

Dalton Trans., 2013,42, 15915-15918

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Palladium- or proton-induced submicro spherical aggregation of macrocyclic amphiphiles in aqueous solution

S. Tashiro, R. Kubota, M. Kawagoe and M. Shionoya, Dalton Trans., 2013, 42, 15915 DOI: 10.1039/C3DT51827B

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