This review highlights recent advances in the atroposelective preparation of axially chiral azole derivatives, emphasizing mechanistic insights and synthetic applications in the development of this class of five-membered heterocyclic frameworks.
The aerobic oxidation of 2,3-dihydroquinazolin-4(1H)-ones and hantzsch 1,4-dihydropyridines in the presence of layered double hydroxides as laccase mimicking nanozymes is describe.
This paper reports a new method for cross-linking rubbers and its application to direct adhesion, by introducing triazolinedione moieties into a polyisoprene followed by adding zinc dimethacrylate with the aim of forming dissociative cross-links.
This highlight provides an account of the discovery and advances in the tyrosine-click (Y-click) reaction and its extensive application in the mapping of proteins, imaging of living cells, and in the fields of analytical and medicinal chemistry.
A swift C–H amination protocol is reported for alkylbenzenes, which shows a remarkable discrimination of C–H bonds, following small differences in substitution pattern. This is rationalized by an unusual rate-determining hydride transfer.