Unleashing the potentiality of metals: synergistic catalysis with light and electricity

Zhengjia Shen, Jia-Lin Tu and Binbin Huang

Org. Chem. Front., 2024, 11, 4024
DOI: 10.1039/D4QO00797B

Visible light-mediated decarboxylative allylic alkylation of Morita–Baylis–Hillman acetates with unactivated aliphatic acids

Hui Zhang, Dan Yang, Yu-Tong Mei, Zi-Yi Guo, Qiu-Yao Hou, Yu-Xuan Zheng, Lin-Hai Jing, De-Jun Cheng and Ming-Song Shi

Org. Biomol. Chem., 2025
DOI: 10.1039/D4OB02036G

Photoinduced decarboxylative radical cascade alkylation/cyclization of benzimidazole derivatives with an aliphatic carboxylic acid via ligand-to-iron charge transfer

Yan Xu, ChenJing Wang, Chun Lv, Jianjie Wang, Qian Zhang, Jiayang Wang, Run-Pu Shen, Bin Sun and Can Jin

New J. Chem., 2024, 48, 14684
DOI: 10.1039/D4NJ02450H

Photoinduced difunctionalizations of unactivated olefins enabled by ligand-to-iron charge transfer and functional group migration strategies

Mengqi Luo, Shibo Zhu, Jiawen Yin, Chao Yang, Lin Guo and Wujiong Xia

Org. Chem. Front., 2024, 11, 4748
DOI: 10.1039/D4QO01025F

Iron-catalyzed benzylic C–H thiolation via photoinduced ligand-to-metal charge-transfer

Kaiting Sun, Tianyi Sun, Yuxin Jiang, Jiayue Shi, Wenlu Sun, Youyou Zheng, Zhixuan Wang, Ziyu Li, Xiaoqing Lv, Xingxian Zhang, Fan Luo and Shihui Liu

Chem. Commun., 2024, 60, 5755
DOI: 10.1039/D4CC01574F

Photochemical generation of heteroatom (N, Si, B) or carbon radicals leveraging preinstalled carboxylic acids

Chao Tian and Lei Shi

Org. Chem. Front., 2025, 12, 2838
DOI: 10.1039/D5QO00036J

Photocatalytic decarboxylation of free carboxylic acids and their functionalization

Subal Mondal, Subham Mandal, Soumya Mondal, Siba P. Midya and Pradyut Ghosh

Chem. Commun., 2024, 60, 9645
DOI: 10.1039/D4CC03189J

Iron-catalyzed thiolation of C(sp3)–H with sulfonyl chlorides via photoinduced ligand-to-metal charge transfer

Sheng-Ping Liu, Lan Yang, Yan-Hong He and Zhi Guan

Org. Chem. Front., 2024, 11, 7001
DOI: 10.1039/D4QO01488J

Direct C(sp3)–H functionalization with aryl and alkyl radicals as intermolecular hydrogen atom transfer (HAT) agents

Jia-Lin Tu and Binbin Huang

Chem. Commun., 2024, 60, 11450
DOI: 10.1039/D4CC03383C

Visible-light induced direct C(sp3)–H functionalization: recent advances and future prospects

Jia-Lin Tu, Yining Zhu, Pengcheng Li and Binbin Huang

Org. Chem. Front., 2024, 11, 5278
DOI: 10.1039/D4QO01179A

Photoelectrochemical iron–cobalt synergistic catalysis for C(sp3)–H alkenylation

Jia-Lin Tu, Ao-Men Hu, Chao Yang, Lin Guo and Wujiong Xia

Org. Chem. Front., 2025, 12, 2732
DOI: 10.1039/D5QO00017C

Photoinduced decatungstate-catalyzed C(sp3)–H thioetherification by sulfinate salts

Pengcheng Li, Jia-Lin Tu, Ao-Men Hu, Lin Guo, Chao Yang and Wujiong Xia

Org. Biomol. Chem., 2024, 22, 3420
DOI: 10.1039/D4OB00394B

Iron-catalyzed C–H bond functionalization into oxime ethers via photo-induced ligand-to-metal charge transfer

Zhijun Hao, Jianguo Han, Xiushan Liu and Huifeng Yue

Org. Biomol. Chem., 2025
DOI: 10.1039/D5OB00346F

Alkylthiolation of Aryl Halides under Electrochemical Conditions

Yingsibing Fan, Tan Zhang, Mengyun Wu, Ping Liu and Peipei Sun

J. Org. Chem., 2024, 89, 17744
DOI: 10.1021/acs.joc.4c02566

Investigation and optimization of metal- and organocatalyzed decarboxylative radical addition of carboxylic acids to Seebach-Beckwith dehydroalanine towards optically pure unnatural amino acids

Ilia Perov, Karizza F. Catenza, Jose Jr. Abucay, Yu-Ting Hsiao and John C. Vederas

Tetrahedron Letters, 2025, 159, 155507
DOI: 10.1016/j.tetlet.2025.155507

Visible Light–Induced Decarboxylative Radical Addition of Heteroaromatic Carboxylic Acids to Alkenes at Room Temperature in Two‐Molecule Photoredox System

Daisuke Suzuki, Ryoga Hashimoto, Toshiki Furutani, Mugen Yamawaki, Hirotsugu Suzuki and Yasuharu Yoshimi

ChemistryOpen, 2025
DOI: 10.1002/open.202500232

Radical-Mediated Decarboxylative C–C and C–S Couplings of Carboxylic Acids via Iron Photocatalysis

Li-Jing Li, Yi Wei, Yu-Lian Zhao, Yang Gao and Xiao-Qiang Hu

Org. Lett., 2024, 26, 1110
DOI: 10.1021/acs.orglett.3c04395

Iron Photocatalysis Enabling Decarboxylative Bromination of (Hetero)Aryl Carboxylic Acids

Xinsheng Deng and Jian Jin

Org. Lett., 2025, 27, 6862
DOI: 10.1021/acs.orglett.5c02030

Bifunctionalization of α-Bromophenone: An Access to Functionalized β-Keto Thiosulfones

Xiaoqing Wen, Mengxin Li, Xiaoyan Peng, Chuanli Liu, Xianglin Zhong, Rui Tan, Hezhong Jiang and Jiahong Li

J. Org. Chem., 2024, 89, 14255
DOI: 10.1021/acs.joc.4c01681

Decarboxylative Alkylation of Carboxylic Acids with Easily Oxidizable Functional Groups Catalyzed by an Imidazole‐Coordinated Fe3 Cluster under Visible Light Irradiation

Sota Tamaki, Tetsuro Kusamoto and Hayato Tsurugi

Chemistry A European J, 2024, 30
DOI: 10.1002/chem.202402705

Mixed‐Metal Ce‐Zr‐Mn Clusters as Photo‐Catalysts for Decarboxylative Functionalization of Carboxylic Acids

Sota Tamaki, Riina Kuwata, Shuto Wakita, Yasuko Osakada, Mamoru Fujitsuka, Tetsuro Kusamoto, Kazushi Mashima and Hayato Tsurugi

Angew Chem Int Ed, 2025, 64
DOI: 10.1002/anie.202505639

Visible Light‐Driven Iron‐Catalyzed Decarboxylative Cyclization Reaction for Synthesis of 3‐Amino‐2,3‐Dihydrobenzofuran Derivatives from 2‐Carboxymethoxybenzaldehydes and Aryl Amines

Wenli Sheng, Zhenyu Jiang, Qingyan Liu and Junmin Chen

Adv Synth Catal, 2025, 367
DOI: 10.1002/adsc.202401593

Iron‐Catalyzed, Light‐Driven Decarboxylative Alkoxyamination

Milan Innocent, Clément Tanguy, Sigrid Gavelle, Thomas Aubineau and Amandine Guérinot

Chemistry A European J, 2024, 30
DOI: 10.1002/chem.202401252

Bis(phenylsulfonyl)sulfide as a Bifunctional Single‐Sulfur Source for the Rapid Assembly of Unsymmetric Diaryl Sulfides Enabled by Copper Catalyst

Jianbo Wang, Yong Zhou, Chaoqun Huang, Huailin Pang and Pengmian Huang

ChemistrySelect, 2024, 9
DOI: 10.1002/slct.202404855

Iron-Catalyzed SO2-Retaining Smiles Rearrangement through Decarboxylation

Liang Zhang, Yahao Huang and Peng Hu

Org. Lett., 2024, 26, 10940
DOI: 10.1021/acs.orglett.4c04107

Photoinduced C−O Bond Formation through C−C Bond Cleavage of Alcohols by Suppressing Alcohol Oxidation

Qiang Wu and Peng Hu

Adv Synth Catal, 2024, 366, 1595
DOI: 10.1002/adsc.202301437

Photoinduced ligand-to-copper charge transfer for decarboxylative hydrogenation of aromatic carboxylic acids

Zhengjia Shen, Jiani Wei, Xue Hu, Zimu Gu, Qiqi Shao, Xuan Chen, Mingming Wang and Dongliang Zhang

Tetrahedron, 2025, 175, 134536
DOI: 10.1016/j.tet.2025.134536

Iron-catalyzed fluoroalkylative alkylsulfonylation of alkenes via radical-anion relay

Xiaoya Hou, Hongchi Liu and Hanmin Huang

Nat Commun, 2024, 15
DOI: 10.1038/s41467-024-45867-y

Iron Photocatalysis for C─H Functionalizations

Silvia Cattani, Gianmarco Pisanò and Gianpiero Cera

Asian J Org Chem, 2025, 14
DOI: 10.1002/ajoc.202500314

Mixed‐Metal Ce‐Zr‐Mn Clusters as Photo‐Catalysts for Decarboxylative Functionalization of Carboxylic Acids

Sota Tamaki, Riina Kuwata, Shuto Wakita, Yasuko Osakada, Mamoru Fujitsuka, Tetsuro Kusamoto, Kazushi Mashima and Hayato Tsurugi

Angewandte Chemie, 2025, 137
DOI: 10.1002/ange.202505639

Advances and perspectives on photochemical/electrochemical synthesis of nitrogen, sulfur, and phosphorus heteroatom containing compounds from biomass-based feedstocks

Hanjing Tian, Anping Wang, Hu Pan, Heng Zhang and Song Yang

Industrial Crops and Products, 2024, 222, 119738
DOI: 10.1016/j.indcrop.2024.119738

Iron-Photocatalyzed Decarboxylative Alkylation of Carboxylic Acids with Morita–Baylis–Hillman Acetates

Yanli Yin, Fang Chen, Dong Chen, Peizhong Xie, Dongping Wang and Teck-Peng Loh

Org. Lett., 2025, 27, 269
DOI: 10.1021/acs.orglett.4c04267

Light‐Induced Direct Decarboxylative Functionalization of Aromatic Carboxylic Acids

Jia‐Lin Tu, Zhengjia Shen and Binbin Huang

Adv Synth Catal, 2024, 366, 4263
DOI: 10.1002/adsc.202400573

Photoinduced Ligand-to-Copper Charge Transfer for Aryl Decarboxylative Allylation, Thiolation, and Bromination

Ao-Men Hu, Jia-Lin Tu, Ke Wang, Jiawen Yin, Lin Guo, Chao Yang and Wujiong Xia

Org. Lett., 2024, 26, 8572
DOI: 10.1021/acs.orglett.4c03188

Electrochemical Aryl(alkyl)thiolation on α-C–H Bond of Ethers to Access O,S-Acetals

Mengyun Wu, Mingqi Chen, Wenhui Wang, Ping Liu and Peipei Sun

J. Org. Chem., 2025, 90, 7351
DOI: 10.1021/acs.joc.5c00628

Construction of C−S and C−Se Bonds from Unstrained Ketone Precursors under Photoredox Catalysis

Hao Wu, Shuguang Chen, Chunni Liu, Quansheng Zhao, Zhen Wang, Qiren Jin, Shijie Sun, Jing Guo, Xinwei He, Patrick J Walsh and Yongjia Shang

Angewandte Chemie, 2024, 136
DOI: 10.1002/ange.202314790

Construction of C−S and C−Se Bonds from Unstrained Ketone Precursors under Photoredox Catalysis

Hao Wu, Shuguang Chen, Chunni Liu, Quansheng Zhao, Zhen Wang, Qiren Jin, Shijie Sun, Jing Guo, Xinwei He, Patrick J Walsh and Yongjia Shang

Angew Chem Int Ed, 2024, 63
DOI: 10.1002/anie.202314790

Iron-Catalyzed Multicomponent C–H Alkylation of in Situ Generated Imines via Photoinduced Ligand-to-Metal Charge Transfer

Pengcheng Li, Jia-Lin Tu, Ao-Men Hu, Yining Zhu, Jiawen Yin, Lin Guo, Chao Yang and Wujiong Xia

Org. Lett., 2024, 26, 6347
DOI: 10.1021/acs.orglett.4c01986

Synthesis and modification of carbohydrates using metallaphotoredox catalysis and photoexcited-state transition metal catalysis

Jing Wang, Fan Zhou, Yuping Xu and Lei Zhang

Sustainable Chemistry and Pharmacy, 2025, 43, 101855
DOI: 10.1016/j.scp.2024.101855