Deborah Brazzolotto, Marcello Gennari, Nicolas Queyriaux, Trevor R. Simmons, Jacques Pécaut, Serhiy Demeshko, Franc Meyer, Maylis Orio, Vincent Artero and Carole Duboc

Nature Chem, 2016, 8, 1054
DOI: 10.1038/nchem.2575

Syntheses, characterization and reactivity of dinuclear ruthenium-nickel complexes with hexane-2,5-dione bis(thiosemicarbazonato) ligands

Duo-Wen Fang, Ai-Quan Jia, Xian-Ping Dong, Zhifeng Xin and Qian-Feng Zhang

Journal of Organometallic Chemistry, 2018, 871, 122
DOI: 10.1016/j.jorganchem.2018.07.006

Hydrogen Evolution from Aqueous Solutions Mediated by a Heterogenized [NiFe]‐Hydrogenase Model: Low pH Enables Catalysis through an Enzyme‐Relevant Mechanism

Md Estak Ahmed, Samir Chattopadhyay, Lianke Wang, Deborah Brazzolotto, Debajyoti Pramanik, Dmitry Aldakov, Jennifer Fize, Adina Morozan, Marcello Gennari, Carole Duboc, Abhishek Dey and Vincent Artero

Angewandte Chemie, 2018, 130, 16233
DOI: 10.1002/ange.201808215

DFT Study on Fe(IV)-Peroxo Formation and H Atom Transfer Triggered O2 Activation by NiFe Complex

Miho Isegawa, Akhilesh K. Sharma, Seiji Ogo and Keiji Morokuma

Organometallics, 2018, 37, 1534
DOI: 10.1021/acs.organomet.8b00098

Identifying a Real Catalyst of [NiFe]‐Hydrogenase Mimic for Exceptional H2 Photogeneration

Xu‐Zhe Wang, Shu‐Lin Meng, Hongyan Xiao, Ke Feng, Yang Wang, Jing‐Xin Jian, Xu‐Bing Li, Chen‐Ho Tung and Li‐Zhu Wu

Angew Chem Int Ed, 2020, 59, 18400
DOI: 10.1002/anie.202006593

NiI/RuII Model for the Ni–L State of the [NiFe]Hydrogenases: Synthesis, Spectroscopy, and Reactivity

Geoffrey M. Chambers, Joyee Mitra, Thomas B. Rauchfuss and Matthias Stein

Inorg. Chem., 2014, 53, 4243
DOI: 10.1021/ic500389p

Synthesis and properties of a molybdenum Schiff base electrocatalyst for generating hydrogen from acetic acid

Jie-Ping Cao, Jia-Xing Zhao, Hai-Xia Lu and Shu-Zhong Zhan

Transition Met Chem, 2014, 39, 933
DOI: 10.1007/s11243-014-9878-x

Group VIII carbamoyl complexes as catalysts for alkyne hydrocarboxylation and electrochemical proton reduction

Chandan Kr Barik, Malcolm E. Tessensohn, Richard D. Webster and Weng Kee Leong

Journal of Organometallic Chemistry, 2019, 889, 40
DOI: 10.1016/j.jorganchem.2019.03.019

Mimicking hydrogenases: From biomimetics to artificial enzymes

Trevor R. Simmons, Gustav Berggren, Marine Bacchi, Marc Fontecave and Vincent Artero

Coordination Chemistry Reviews, 2014, 270-271, 127
DOI: 10.1016/j.ccr.2013.12.018

Hydrogen Evolution from Aqueous Solutions Mediated by a Heterogenized [NiFe]‐Hydrogenase Model: Low pH Enables Catalysis through an Enzyme‐Relevant Mechanism

Md Estak Ahmed, Samir Chattopadhyay, Lianke Wang, Deborah Brazzolotto, Debajyoti Pramanik, Dmitry Aldakov, Jennifer Fize, Adina Morozan, Marcello Gennari, Carole Duboc, Abhishek Dey and Vincent Artero

Angew Chem Int Ed, 2018, 57, 16001
DOI: 10.1002/anie.201808215

De novo design of functional proteins: Toward artificial hydrogenases

Marina Faiella, Anindya Roy, Dayn Sommer and Giovanna Ghirlanda

Biopolymers, 2013, 100, 558
DOI: 10.1002/bip.22420

Artificial Small Molecules as Cofactors and Biomacromolecular Building Blocks in Synthetic Biology: Design, Synthesis, Applications, and Challenges

Fenghua Liu, Lingling He, Sheng Dong, Jinsong Xuan, Qiu Cui and Yingang Feng

Molecules, 2023, 28, 5850
DOI: 10.3390/molecules28155850

Understanding and Design of Bidirectional and Reversible Catalysts of Multielectron, Multistep Reactions

Vincent Fourmond, Eric S. Wiedner, Wendy J. Shaw and Christophe Léger

J. Am. Chem. Soc., 2019, 141, 11269
DOI: 10.1021/jacs.9b04854

Electron and Hydride Transfer in a Redox-Active NiFe Hydride Complex: A DFT Study

Miho Isegawa, Akhilesh K. Sharma, Seiji Ogo and Keiji Morokuma

ACS Catal., 2018, 8, 10419
DOI: 10.1021/acscatal.8b02368

Learning from nature: Understanding hydrogenase enzyme using computational approach

Siyao Qiu, Qinye Li, Yongjun Xu, Shaohua Shen and Chenghua Sun

WIREs Comput Mol Sci, 2020, 10
DOI: 10.1002/wcms.1422

Reversible catalysis

Vincent Fourmond, Nicolas Plumeré and Christophe Léger

Nat Rev Chem, 2021, 5, 348
DOI: 10.1038/s41570-021-00268-3

Multimetallic Catalysis Based on Heterometallic Complexes and Clusters

Paulin Buchwalter, Jacky Rosé and Pierre Braunstein

Chem. Rev., 2015, 115, 28
DOI: 10.1021/cr500208k

A molecular molybdenum electrocatalyst for generating hydrogen from acetic acid or water

Jie-Ping Cao, Ling-Ling Zhou, Ling-Zhi Fu and Shuzhong Zhan

Journal of Power Sources, 2014, 272, 169
DOI: 10.1016/j.jpowsour.2014.08.078

Dinuclear Nickel Complexes of Thiolate-Functionalized Carbene Ligands and Their Electrochemical Properties

Siyuan Luo, Maxime A. Siegler and Elisabeth Bouwman

Organometallics, 2018, 37, 740
DOI: 10.1021/acs.organomet.7b00576

A dinuclear triazenido–copper complex: A new molecular electro-catalyst for generating hydrogen from acetic acid or water

Jie-Ping Cao, Ting Fang, Zhuo-Qiang Wang, Yan-Wei Ren and Shuzhong Zhan

Journal of Molecular Catalysis A: Chemical, 2014, 391, 191
DOI: 10.1016/j.molcata.2014.04.034

A molecular molybdenum–schiff base electro-catalyst for generating hydrogen from acetic acid or water

Jie-Ping Cao, Ting Fang, Ling-Ling Zhou, Ling-Zhi Fu and Shuzhong Zhan

Electrochimica Acta, 2014, 147, 129
DOI: 10.1016/j.electacta.2014.09.089

Energy-Efficient Hydrogen Evolution by Fe–S Electrocatalysts: Mechanistic Investigations

Kai-Ti Chu, Yu-Chiao Liu, Min-Wen Chung, Agus Riyanto Poerwoprajitno, Gene-Hsiang Lee and Ming-Hsi Chiang

Inorg. Chem., 2018, 57, 7620
DOI: 10.1021/acs.inorgchem.8b00543

Photocatalytic hydrogen production with alkylated nickel bis-dithiolene complexes

Athanasios Zarkadoulas, Eugenia Koutsouri, Emmanouil Semidalas, Vassilis Psycharis, Catherine P. Raptopoulou and Christiana A. Mitsopoulou

Polyhedron, 2018, 152, 138
DOI: 10.1016/j.poly.2018.06.029

Molecular Cobalt Complexes with Pendant Amines for Selective Electrocatalytic Reduction of Carbon Dioxide to Formic Acid

Souvik Roy, Bhaskar Sharma, Jacques Pécaut, Philippe Simon, Marc Fontecave, Phong D. Tran, Etienne Derat and Vincent Artero

J. Am. Chem. Soc., 2017, 139, 3685
DOI: 10.1021/jacs.6b11474

Mono-nuclear ruthenium catalyst for hydrogen evolution

Vishakha Kaim, Meenakshi Joshi, Matthias Stein and Sandeep Kaur-Ghumaan

International Journal of Hydrogen Energy, 2023, 48, 30718
DOI: 10.1016/j.ijhydene.2023.04.135

Nickel Complexes of Pyridine‐Functionalized N‐Heterocyclic Carbenes: Syntheses, Structures, and Activity in Electrocatalytic Hydrogen Production

Siyuan Luo, Maxime A. Siegler and Elisabeth Bouwman

Eur J Inorg Chem, 2016, 2016, 4693
DOI: 10.1002/ejic.201600917

Effect of metal centers on electrocatalytic hydrogen generation catalyzed by coordinatively saturated metal-1,10-phenanthroline complexes

Su-Ping Luo, Qiu-Xia Peng, Jing Liu and Shu-Zhong Zhan

Polyhedron, 2018, 139, 44
DOI: 10.1016/j.poly.2017.10.010

Synthetic Active Site Model of the [NiFeSe] Hydrogenase

Claire Wombwell and Erwin Reisner

Chemistry A European J, 2015, 21, 8096
DOI: 10.1002/chem.201500311

Nickel complexes as molecular catalysts for water splitting and CO2 reduction

Jia-Wei Wang, Wen-Ju Liu, Di-Chang Zhong and Tong-Bu Lu

Coordination Chemistry Reviews, 2019, 378, 237
DOI: 10.1016/j.ccr.2017.12.009

First mononuclear copper(II) electro-catalyst for catalyzing hydrogen evolution from acetic acid and water

Jie-Ping Cao, Ting Fang, Ling-Zhi Fu, Ling-Ling Zhou and Shu-Zhong Zhan

International Journal of Hydrogen Energy, 2014, 39, 13972
DOI: 10.1016/j.ijhydene.2014.07.030

Heterobimetallic Models of the [NiFe] Hydrogenases: A Structural and Spectroscopic Comparison

Shelby L. Behnke and Hannah S. Shafaat

Comments on Inorganic Chemistry, 2016, 36, 123
DOI: 10.1080/02603594.2015.1108914

Mechanistic insights into consecutive 2e− and 2H+ reactions of hydrogenase mimic

Xu-Zhe Wang, Shu-Lin Meng, Jianguo Liu, Can Yu, Chen Ye, Hai-Xu Wang, Maofu Pang, Xin Yu, Wenguang Wang, Xu-Bing Li, Chen-Ho Tung and Li-Zhu Wu

Chem, 2023, 9, 2610
DOI: 10.1016/j.chempr.2023.05.010

Identifying a Real Catalyst of [NiFe]‐Hydrogenase Mimic for Exceptional H2 Photogeneration

Xu‐Zhe Wang, Shu‐Lin Meng, Hongyan Xiao, Ke Feng, Yang Wang, Jing‐Xin Jian, Xu‐Bing Li, Chen‐Ho Tung and Li‐Zhu Wu

Angewandte Chemie, 2020, 132, 18558
DOI: 10.1002/ange.202006593

A nickel molecular electro-catalyst for generating hydrogen from acetic acid or water

Jie-Ping Cao, Ting Fang, Ling-Zhi Fu, Ling-Ling Zhou and Shuzhong Zhan

International Journal of Hydrogen Energy, 2014, 39, 10980
DOI: 10.1016/j.ijhydene.2014.05.082

Synthesis and electrocatalytic properties of a cobalt(II) complex supported by N,N-dimethylethylenediamino-N,N-bis(2-tert-butyl-4-ethylphenol)

Yun-Xiao Zhang, Chen-Neng Lin, Jing Liu, Shu-Zhong Zhan and Xiao-Hua Xie

Transit Met Chem, 2016, 41, 623
DOI: 10.1007/s11243-016-0061-4

Proton‐Reduction Reaction Catalyzed by Homoleptic Nickel–bis‐1,2‐dithiolate Complexes: Experimental and Theoretical Mechanistic Investigations

Athanasios Zarkadoulas, Martin J. Field, Vincent Artero and Christiana A. Mitsopoulou

ChemCatChem, 2017, 9, 2308
DOI: 10.1002/cctc.201601399

Effect of Ligand Backbone on the Electrochemical Hydrogen Evolution Reaction and Hydrogen-Atom-Transfer Reactivity Using a Nickel Polypyridine Quinoline Complex

Sabarni Paul, Subhankar Sutradhar, Aniruddha Paik, Amit Biswas, Soumadip Das, Chandan Das, Rajib Maity, Alok Mahata, Siba P. Midya, Bholanath Maity and Sujoy Rana

Inorg. Chem., 2025, 64, 7988
DOI: 10.1021/acs.inorgchem.4c05512

New Rh2(II,II) Architecture for the Catalytic Reduction of H+

Travis A. White, Suzanne E. Witt, Zhanyong Li, Kim R. Dunbar and Claudia Turro

Inorg. Chem., 2015, 54, 10042
DOI: 10.1021/acs.inorgchem.5b01823

Katalytische Wasserstoffoxidation: Beginn einer neuen Eisenzeit

Trevor R. Simmons and Vincent Artero

Angewandte Chemie, 2013, 125, 6259
DOI: 10.1002/ange.201302908

Synthesis and studies of a molecular molybdenum–Schiff base electrocatalyst for generating hydrogen from organic acid or water

Ting Fang, Hai-Xia Lu, Jia-Xing Zhao and Shu-Zhong Zhan

Inorganic Chemistry Communications, 2015, 51, 66
DOI: 10.1016/j.inoche.2014.11.009

Synthesis and studies of a molecular copper(I)-triazenido electrocatalyst for catalyzing hydrogen evolution from acetic acid and water

Ting Fang, Ling-Ling Zhou, Ling-Zhi Fu, Shu-Zhong Zhan and Qi-Ying Lv