Investigation of the fluorolysis of magnesium methoxide

Stefan Wuttke, Anja Lehmann, Gudrun Scholz, Michael Feist, Anton Dimitrov, Sergey I. Troyanov and Erhard Kemnitz

Dalton Trans., 2009, 4729
DOI: 10.1039/b901030k

The non-aqueous fluorolytic sol–gel synthesis of nanoscaled metal fluorides

Erhard Kemnitz and Johannes Noack

Dalton Trans., 2015, 44, 19411
DOI: 10.1039/C5DT00914F

Sub-nano MgF2 embedded in carbon nanofibers and electrospun MgF2 nanofibers by one-step electrospinning as highly efficient catalysts for 1,1,1-trifluoroethane dehydrofluorination

Wenfeng Han, Chunpeng Zhang, Haili Wang, Shenglan Zhou, Haodong Tang, Luteng Yang and Zhikun Wang

Catal. Sci. Technol., 2017, 7, 6000
DOI: 10.1039/C7CY02056B

Sols of nanosized magnesium fluoride: formation and stabilisation of nanoparticles

Johannes Noack, Franziska Emmerling, Holm Kirmse and Erhard Kemnitz

J. Mater. Chem., 2011, 21, 15015
DOI: 10.1039/c1jm11943e

NMR parameters in alkali, alkaline earth and rare earth fluorides from first principle calculations

Aymeric Sadoc, Monique Body, Christophe Legein, Mamata Biswal, Franck Fayon, Xavier Rocquefelte and Florent Boucher

Phys. Chem. Chem. Phys., 2011, 13, 18539
DOI: 10.1039/c1cp21253b

Nanoscale metal fluorides: a new class of heterogeneous catalysts

Erhard Kemnitz

Catal. Sci. Technol., 2015, 5, 786
DOI: 10.1039/C4CY01397B

Novel sol–gel prepared zinc fluoride: synthesis, characterisation and acid–base sites analysis

Ying Guo, Stefan Wuttke, Alexandre Vimont, Marco Daturi, Jean-Claude Lavalley, Katharina Teinz and Erhard Kemnitz

J. Mater. Chem., 2012, 22, 14587
DOI: 10.1039/c2jm31357j

The fluorolytic sol–gel route to metal fluorides—a versatile process opening a variety of application fields

Stephan Rüdiger and Erhard Kemnitz

Dalton Trans., 2008, 1117
DOI: 10.1039/b716483a

Metal fluoride materials with complex pore structure and organic functionality

Johannes Noack, Katharina Teinz, Christian Schaumberg, Carsten Fritz, Stephan Rüdiger and Erhard Kemnitz

J. Mater. Chem., 2011, 21, 334
DOI: 10.1039/C0JM02204G

Layered double alkoxides a novel group of layered double hydroxides without water content

Gábor Varga, Márton Szabados, Ákos Kukovecz, Zoltán Kónya, Tamás Varga, Pál Sipos and István Pálinkó

Materials Research Letters, 2020, 8, 68
DOI: 10.1080/21663831.2019.1700199

Infrared Investigation of the Acid and Basic Properties of a Sol−Gel Prepared MgF2

Stefan Wuttke, Alexandre Vimont, Jean-Claude Lavalley, Marco Daturi and Erhard Kemnitz

J. Phys. Chem. C, 2010, 114, 5113
DOI: 10.1021/jp911584h

Selective Chemical Filters for VOF3: Tailoring MgF2 Filter Selectivity through Surface Chemistry

Laurent Jouffret, Jean-Michel Hiltbrunner, Elodie Petit, Ania Selmi, Bertrand Morel and Marc Dubois

Surfaces, 2023, 6, 480
DOI: 10.3390/surfaces6040032

SiO2-template synthesis of mesoporous MgF2 highly effective for Cl/F exchange reaction

Miao Chen, Jia-Min Jin, Sheng-Da Lin, Ying Li, Wu-Can Liu, Li Guo, Ling Li and Xiao-Nian Li

Journal of Fluorine Chemistry, 2013, 150, 46
DOI: 10.1016/j.jfluchem.2013.03.003

Fluorine-modified Mg–Al mixed oxides: A solid base with variable basic sites and tunable basicity

Gongde Wu, Xiaoli Wang, Wei Wei and Yuhan Sun

Applied Catalysis A: General, 2010, 377, 107
DOI: 10.1016/j.apcata.2010.01.023

Control of the Shell Structural Properties and Cavity Diameter of Hollow Magnesium Fluoride Particles

Asep Bayu Dani Nandiyanto, Takashi Ogi and Kikuo Okuyama

ACS Appl. Mater. Interfaces, 2014, 6, 4418
DOI: 10.1021/am500139m

Local fluorine environments in nanoscopic magnesium hydr(oxide) fluorides studied by 19F MAS NMR

G. Scholz, C. Stosiek, J. Noack and E. Kemnitz

Journal of Fluorine Chemistry, 2011, 132, 1079
DOI: 10.1016/j.jfluchem.2011.06.024

Iron(III) fluoride synthesized by a fluorolysis method and its electrochemical properties as a positive electrode material for lithium secondary batteries

Shinya Tawa, Takayuki Yamamoto, Kazuhiko Matsumoto and Rika Hagiwara

Journal of Fluorine Chemistry, 2016, 184, 75
DOI: 10.1016/j.jfluchem.2016.02.009

Preparation and characterization of chromium-doped magnesium fluoride catalysts via an aqueous sol–gel method

Haodong Tang, Chaoyu Zou, Tao Hu, Nan Zhou, Yuzhen Li, Lichun Li, Wenfeng Han and Ying Li

J Sol-Gel Sci Technol, 2019, 92, 200
DOI: 10.1007/s10971-019-05049-5

Magnesium Hydroxide Fluorides – New Materials with Adjustable Composition and Properties

Gudrun Scholz, Christoph Stosiek, Michael Feist and Erhard Kemnitz

Eur J Inorg Chem, 2012, 2012, 2337
DOI: 10.1002/ejic.201200108

Aluminium(III) fluoride originating from decomposition of hydrazinium fluoroaluminate(III) under oxidative conditions: Syntheses, X-ray photoelectron spectroscopy and some catalytic reactions

Tomaž Skapin, Zoran Mazej, Anna Makarowicz, Adolf Jesih, Mahmood Nickkho-Amiry, Sven L.M. Schroeder, Norbert Weiher, Boris Žemva and John M. Winfield

Journal of Fluorine Chemistry, 2011, 132, 703
DOI: 10.1016/j.jfluchem.2011.04.013

Study of the effect of the precursor salt on the synthesis of magnesium fluoride and its influence on the optical properties

Noé Zavala-Cuéllar, Christian Gómez-Solís, M.A. Vallejo, Miguel Ruíz-Gómez, Pablo Cerón and Manuel I. León-Madrid

Ceramics International, 2024, 50, 24939
DOI: 10.1016/j.ceramint.2024.03.103

Surface reactivity of uranium hexafluoride (UF6)

Bertrand Morel, Ania Selmi, Laurent Moch, Jean-Michel Hiltbrunner, Mickael Achour, Rachid Benzouaa, Aurélien Bock, Laurent Jouffret, Pierre Bonnet, André Hamwi and Marc Dubois

Comptes Rendus. Chimie, 2018, 21, 782
DOI: 10.1016/j.crci.2018.05.006

Investigating acidity of metal fluoride surfaces by spectroscopic and chemical methods

John M. Winfield

Journal of Fluorine Chemistry, 2009, 130, 1069
DOI: 10.1016/j.jfluchem.2009.07.012

An epoxide ring-opening reaction by using sol–gel-synthesized palladium supported on a strontium hydroxyl fluoride catalyst

Vaibhav R. Acham, Mohan K. Dongare, Erhard Kemnitz and Shubhangi B. Umbarkar

Comptes Rendus. Chimie, 2016, 19, 1237
DOI: 10.1016/j.crci.2016.07.008

Highly selective metal fluoride catalysts for the dehydrohalogenation of 3-chloro-1,1,1,3-tetrafluorobutane

Katharina Teinz, Stefan Wuttke, Fabian Börno, Johannes Eicher and Erhard Kemnitz

Journal of Catalysis, 2011, 282, 175
DOI: 10.1016/j.jcat.2011.06.013

A comparative study of surface acidity in the amorphous, high surface area solids, aluminium fluoride, magnesium fluoride and magnesium fluoride containing iron(III) or aluminium(III) fluorides

Mahmood Nickkho-Amiry, Gehan Eltanany, Stefan Wuttke, Stephan Rüdiger, Erhard Kemnitz and John M. Winfield

Journal of Fluorine Chemistry, 2008, 129, 366
DOI: 10.1016/j.jfluchem.2008.01.017

Nano metal fluorides: small particles with great properties

Erhard Kemnitz, Stefan Mahn and Thoralf Krahl

ChemTexts, 2020, 6
DOI: 10.1007/s40828-020-00115-w

Local Structural Changes in Aluminum Isopropoxide Fluoride Xerogels and Solids as a Consequence of the Progressive Fluorination Degree

R. König, G. Scholz and E. Kemnitz

J. Phys. Chem. C, 2009, 113, 6426
DOI: 10.1021/jp810190k

Crystalline aluminium hydroxy fluorides—Suitable reference compounds for 19F chemical shift trend analysis of related amorphous solids

René König, Gudrun Scholz, Rainer Bertram and Erhard Kemnitz

Journal of Fluorine Chemistry, 2008, 129, 598
DOI: 10.1016/j.jfluchem.2008.04.015

Sol–Gel Synthesis and Characterisation of Nanoscopic FeF3‐MgF2 Heterogeneous Catalysts with Bi‐Acidic Properties

Ying Guo, Piotr Gaczyński, Klaus‐Dieter Becker and Erhard Kemnitz

ChemCatChem, 2013, 5, 2223
DOI: 10.1002/cctc.201300115

Insight Into the Role of Polymers in the Bulk Synthesis of MgF2 for the Fluorination of 2‐Chloropyridine

Julien Dieu, Francesca François, Anne Sophie Mamede, Isabelle Batonneau Gener, Sagrario Pascual, Vincent Maisonneuve, Amandine Guiet and Sylvette Brunet

ChemCatChem, 2025, 17
DOI: 10.1002/cctc.202501064

Sol–gel prepared nanoscopic metal fluorides – a new class of tunable acid–base catalysts

S. Wuttke, S.M. Coman, J. Kröhnert, F.C. Jentoft and E. Kemnitz

Catalysis Today, 2010, 152, 2
DOI: 10.1016/j.cattod.2009.10.008

Palladium Supported on Fluorinated Magnesium Hydroxide: An Efficient Catalyst for Hydrogenation under Ambient Conditions

Reshma S. Kokane, Vaibhav R. Acham, Atul B. Kulal, Erhard Kemnitz, Mohan K. Dongare and Shubhangi B. Umbarkar

ChemistrySelect, 2017, 2, 10618
DOI: 10.1002/slct.201702217

Tailor‐Made MgF2‐Based Catalysts by Sol–Gel Synthesis

Erhard Kemnitz, Stefan Wuttke and Simona M. Coman

Eur J Inorg Chem, 2011, 2011, 4773
DOI: 10.1002/ejic.201100539

The origin of increased chemoselectivity of platinum supported on magnesium fluoride in the hydrogenation of chloronitrobenzene

Mariusz Pietrowski and Maria Wojciechowska

Catalysis Today, 2011, 169, 217
DOI: 10.1016/j.cattod.2010.09.021

Hollownano-MgF2 supported catalysts: Highly active and stable in gas-phase dehydrofluorination of 1,1,1,3,3-pentafluoropropane

Zhaohua Jia, Wei Mao, Yanbo Bai, Bo Wang, Hui Ma, Chen Li and Jian Lu

Applied Catalysis B: Environmental, 2018, 238, 599
DOI: 10.1016/j.apcatb.2018.07.067

High specific surface area metal fluorides as catalysts for the fluorination of 2-chloropyridine by HF

Arnaud Astruc, Cindy Cochon, Samuel Dessources, Stéphane Célérier and Sylvette Brunet

Applied Catalysis A: General, 2013, 453, 20
DOI: 10.1016/j.apcata.2012.11.043

Controlled Morphology Synthesis of Nanostructured β-AlF3–x(OH)x with Tunable Specific Surface Area

Valentine Camus-Génot, Amandine Guiet, Jérôme Lhoste, Franck Fayon, Monique Body, Stéphanie Kodjikian, Romain Moury, Marc Leblanc, Jean Louis Bobet, Christophe Legein and Vincent Maisonneuve

Crystal Growth & Design, 2021, 21, 5914
DOI: 10.1021/acs.cgd.1c00808

The Effects of Various Parameters of the Microwave-Assisted Solvothermal Synthesis on the Specific Surface Area and Catalytic Performance of MgF2 Nanoparticles

Yawen Wang, Zahra Gohari Bajestani, Jérôme Lhoste, Sandy Auguste, Annie Hémon-Ribaud, Monique Body, Christophe Legein, Vincent Maisonneuve, Amandine Guiet and Sylvette Brunet

Materials, 2020, 13, 3566
DOI: 10.3390/ma13163566

Novel Sol–Gel Synthesis of Acidic MgF2−x(OH)x Materials

Stefan Wuttke, Simona M. Coman, Gudrun Scholz, Holm Kirmse, Alexandré Vimont, Maro Daturi, Sven L. M. Schroeder and Erhard Kemnitz

Chemistry A European J, 2008, 14, 11488
DOI: 10.1002/chem.200801702

Evaluation of novel nanoscaled metal fluorides on their ability to remineralize enamel caries lesions

Matthias Zirk, Sandra Schievelkamp, Erhard Kemnitz, Julian Lausch, Richard J. Wierichs, Marcella Esteves-Oliveira and Hendrik Meyer-Lueckel

Sci Rep, 2019, 9
DOI: 10.1038/s41598-018-38225-8