Issue 1, 2024

Designed metal–organic π-clusters combining the aromaticity of the metal cluster and ligands for a third-order nonlinear optical response

Abstract

The pivotal role of clusters and aromaticity in chemistry is undeniable, but there remains a gap in systematically understanding the aromaticity of metal–organic clusters. Herein, this article presents a novel metal–organic π-cluster, melding both metal–organic chemistry and aromaticity, to guide the construction of structurally stable Os-organic π-clusters. An in-depth analysis of these clusters reveals their bonding attributes, π-electronic composition, and origins of aromaticity, thereby confirming their unique metal–organic π-cluster properties. Furthermore, the Os5 cluster exhibits a promising third-order nonlinear optical (NLO) response, attributable to its narrow band gap and uniform electron/hole distribution, suggesting its potential as an optical switching material. This research introduces a fresh perspective on clusters, centered on delocalization, and broadens the domain of aromaticity studies. It also presents a novel method for designing efficient third-order NLO materials through consideration of the structure–activity relationship.

Graphical abstract: Designed metal–organic π-clusters combining the aromaticity of the metal cluster and ligands for a third-order nonlinear optical response

  • This article is part of the themed collection: #MyFirstMH

Supplementary files

Article information

Article type
Communication
Submitted
26 9 2023
Accepted
01 11 2023
First published
03 11 2023

Mater. Horiz., 2024,11, 297-302

Designed metal–organic π-clusters combining the aromaticity of the metal cluster and ligands for a third-order nonlinear optical response

Z. Wang, Y. Yan, J. Chen, Q. Li and J. Zhang, Mater. Horiz., 2024, 11, 297 DOI: 10.1039/D3MH01538F

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