Issue 12, 2023

Transition metal-free and regioselective alkenyl C–S cross-coupling reaction of alkenylsulfonium salts

Abstract

Herein, we report a novel and highly efficient strategy for the construction of alkenyl sulfoxides via transition metal-free C–S cross-coupling of sulfenate anions with alkenylsulfonium salts. This procedure features the capture of in situ generated sulfenate anions from β-sulfinyl esters under mild conditions, which provides an efficient strategy for the synthesis of diverse alkenyl sulfoxides in moderate to good yields.

Graphical abstract: Transition metal-free and regioselective alkenyl C–S cross-coupling reaction of alkenylsulfonium salts

Supplementary files

Article information

Article type
Research Article
Submitted
05 4 2023
Accepted
10 5 2023
First published
23 5 2023

Org. Chem. Front., 2023,10, 2907-2912

Transition metal-free and regioselective alkenyl C–S cross-coupling reaction of alkenylsulfonium salts

Q. Wang, S. Wu, Y. Wang, J. Sun, Y. Han, C. Yan and L. Wang, Org. Chem. Front., 2023, 10, 2907 DOI: 10.1039/D3QO00507K

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