Issue 93, 2021

Steric control of sorting regimes in self-assembled cages

Abstract

Control of self-sorting regimes is achieved through adjustment of steric interactions in self-assembled coordination cages. The self-assembly regime of dynamic mixtures of heteroleptic cages is followed by HPLC to show that statistical or biased distributions can be selectively obtained, including isolation of a single heteroleptic species.

Graphical abstract: Steric control of sorting regimes in self-assembled cages

Supplementary files

Article information

Article type
Communication
Submitted
05 10 2021
Accepted
29 10 2021
First published
29 10 2021

Chem. Commun., 2021,57, 12456-12459

Steric control of sorting regimes in self-assembled cages

S. E. Walker, S. A. Boer, T. Malcomson, M. J. Paterson, K. L. Tuck and D. R. Turner, Chem. Commun., 2021, 57, 12456 DOI: 10.1039/D1CC05610G

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