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Abstract | Cited by

Thioamycolamide A is a biosynthetically unique cytotoxic cyclic microbial lipopeptide that bears a D-configured thiazoline, a thioether bridge, a fatty acid side chain, and a reduced C-terminus. Based on the biosynthetic insights, a concise total synthesis of thioamycolamide A was accomplished.

Graphical abstract: Total synthesis of thioamycolamide A via a biomimetic route

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