Issue 34, 2018

Stereodivergent trifluoromethylation of N-sulfinylimines by fluoroform with either organic-superbase or organometallic-base

Abstract

Here we have successfully demonstrated the first stereodivergent direct nucleophilic trifluoromethylation of N-sulfinylimines using the potent greenhouse gas “HFC-23, fluoroform” with an organic-superbase or an organometallic-base in high yields and selectivity.

Graphical abstract: Stereodivergent trifluoromethylation of N-sulfinylimines by fluoroform with either organic-superbase or organometallic-base

Supplementary files

Article information

Article type
Communication
Submitted
26 2 2018
Accepted
23 3 2018
First published
23 3 2018

Chem. Commun., 2018,54, 4294-4297

Author version available

Stereodivergent trifluoromethylation of N-sulfinylimines by fluoroform with either organic-superbase or organometallic-base

N. Punna, T. Saito, M. Kosobokov, E. Tokunaga, Y. Sumii and N. Shibata, Chem. Commun., 2018, 54, 4294 DOI: 10.1039/C8CC01526K

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