Issue 6, 2017

A facile approach to ketones via Pd-catalyzed sequential carbonylation of olefins with formic acid

Abstract

An effective palladium-catalyzed sequential carbonylation of olefins with formic acid is described. Ketones and the corresponding α,β-enones can be obtained with up to 90% yield. The reaction process is operationally simple and requires no toxic CO.

Graphical abstract: A facile approach to ketones via Pd-catalyzed sequential carbonylation of olefins with formic acid

Supplementary files

Article information

Article type
Research Article
Submitted
09 2 2017
Accepted
22 2 2017
First published
22 2 2017

Org. Chem. Front., 2017,4, 1074-1078

A facile approach to ketones via Pd-catalyzed sequential carbonylation of olefins with formic acid

W. Chang, J. Dai, J. Li, Y. Shi, W. Ren and Y. Shi, Org. Chem. Front., 2017, 4, 1074 DOI: 10.1039/C7QO00111H

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