Issue 14, 2016

Triphenylamine-functionalized tetraphenylpyrazine: facile preparation and multifaceted functionalities

Abstract

Aggregation-induced emission (AIE) is a unique photo-physical phenomenon and has become an emerging and hot research area. With the enthusiastic efforts paid by researchers, hundreds of AIE-active luminogens (AIEgens) have been generated but heterocyclic AIEgens are rarely reported. Recently, we enriched the family of AIEgens and reported a pyrazine-based AIEgen of tetraphenylpyrazine (TPP), which could be facilely functionalized by a post-synthetic strategy. In this work, we further expanded the TPP-based AIE system by covalently attaching one, two or four electron-donating triphenylamine moieties to the TPP core via Suzuki coupling, and TPP–TPA, TPP–2TPA and TPP–4TPA were produced, respectively. Thanks to their donor-π-acceptor structures, these luminogens exhibit multi-functional properties, such as excellent thermal stability (up to 504 °C), large molar absorptivity, bright emission in the solid state (quantum yields up to 35.2%), solvatochromism, and high two-photon absorption cross-sections (up to 480 GM). Furthermore, using TPP–TPA as the emitting layer, a triple-layer device was fabricated and a turn-on voltage, maximum luminance, current efficiency, power efficiency, and external quantum efficiency of 3.7 V, 17 459 cd m−2, 5.49 cd A−1, 3.18 lm W−1 and 2.88% were realized, respectively. These results indicate a huge potential to develop high-tech applications based on these TPP-based AIEgens.

Graphical abstract: Triphenylamine-functionalized tetraphenylpyrazine: facile preparation and multifaceted functionalities

Supplementary files

Article information

Article type
Paper
Submitted
13 10 2015
Accepted
18 11 2015
First published
18 11 2015

J. Mater. Chem. C, 2016,4, 2901-2908

Author version available

Triphenylamine-functionalized tetraphenylpyrazine: facile preparation and multifaceted functionalities

M. Chen, H. Nie, B. Song, L. Li, J. Z. Sun, A. Qin and B. Z. Tang, J. Mater. Chem. C, 2016, 4, 2901 DOI: 10.1039/C5TC03299G

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