Issue 17, 2024

Insights into interfacial mechanisms: CsPbBr3 nanocrystals as sustainable photocatalysts for primary amine oxidation

Abstract

CsPbBr3 nanocrystals (NCs) employed as a photocatalyst resulted in efficient benzylamine oxidation under oxygen atmosphere. Improved reaction yields stem from favorable –NH2 functional group interactions on the NC surface, while additional interactions with –OMe or –SMe functional groups post-product formation result in lower yields. These insights into interfacial interactions and mechanistic aspects advance sustainable chemical transformations through cost-effective and recyclable CsPbBr3 NC-catalyzed primary amine oxidation.

Graphical abstract: Insights into interfacial mechanisms: CsPbBr3 nanocrystals as sustainable photocatalysts for primary amine oxidation

Supplementary files

Article information

Article type
Communication
Submitted
22 11 2023
Accepted
29 1 2024
First published
30 1 2024

Chem. Commun., 2024,60, 2365-2368

Insights into interfacial mechanisms: CsPbBr3 nanocrystals as sustainable photocatalysts for primary amine oxidation

M. Ahlawat and V. Govind Rao, Chem. Commun., 2024, 60, 2365 DOI: 10.1039/D3CC05725A

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