Issue 8, 2024

Reducing delamination of an electron-transporting polymer from a metal oxide for electrochemical applications

Abstract

Delamination of the electron-transporting polymer N2200 from indium tin oxide (ITO) in aqueous electrolytes is mitigated by modifying ITO with an azide-functionalized phosphonic acid (PA) which, upon UV irradiation, reacts with the polymer. The optical, electrochemical, and spectroelectrochemical properties of N2200 thin films are retained in aqueous and non-aqueous media.

Graphical abstract: Reducing delamination of an electron-transporting polymer from a metal oxide for electrochemical applications

Supplementary files

Article information

Article type
Communication
Submitted
01 11 2023
Accepted
18 12 2023
First published
20 12 2023

Chem. Commun., 2024,60, 988-991

Reducing delamination of an electron-transporting polymer from a metal oxide for electrochemical applications

A. A. Mohapatra, W. K. Yual, Y. Zhang, A. A. Samoylov, J. Thurston, C. M. Davis, D. P. McCarthy, A. D. Printz, M. F. Toney, E. L. Ratcliff, N. R. Armstrong, A. L. Greenaway, S. Barlow and S. R. Marder, Chem. Commun., 2024, 60, 988 DOI: 10.1039/D3CC05391A

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