Issue 33, 2023

Role of the energy offset in the charge photogeneration and voltage loss of nonfullerene acceptor-based organic solar cells

Abstract

The trade-off between short-circuit current density (JSC) and open-circuit voltage (VOC) has been one of the largest challenges in improving the power conversion efficiencies (PCEs) of organic solar cells (OSCs). Although the energy offset between the excited and charge transfer (CT) states should remain minimal to achieve a high VOC, a very small energy offset typically leads to degradation of JSC, even when novel nonfullerene acceptors (NFAs), such as Y6, are used. Therefore, understanding the limit to what extent the energy offset can be minimized and the physics underlying the trade-off relationship is important to optimize the design of new materials and further improve the PCEs. This study provides a threshold energy that can ensure high charge photogeneration quantum efficiencies for Y-series NFA-based OSCs and discusses the role of the energy offset in device performances. We found that an insufficient energy offset led to not only slow hole transfer at the donor:acceptor interfaces, but also inefficient long-range spatial dissociation of the CT states and degradation of the fill factor (FF). This study also discusses the interplay of the energy levels of the two NFAs that constitute ternary blend OSCs. We found that, by introducing a low-efficiency NFA into a high-efficiency donor:acceptor blend, the voltage loss can be reduced while maintaining a high charge photogeneration quantum efficiency. Our findings highlight the importance of overcoming the trade-off between FF and VOC for further improving the PCE.

Graphical abstract: Role of the energy offset in the charge photogeneration and voltage loss of nonfullerene acceptor-based organic solar cells

Supplementary files

Article information

Article type
Paper
Submitted
31 3 2023
Accepted
19 6 2023
First published
21 6 2023
This article is Open Access
Creative Commons BY license

J. Mater. Chem. A, 2023,11, 17581-17593

Role of the energy offset in the charge photogeneration and voltage loss of nonfullerene acceptor-based organic solar cells

Y. Tamai, R. Shirouchi, T. Saito, K. Kohzuki and S. Natsuda, J. Mater. Chem. A, 2023, 11, 17581 DOI: 10.1039/D3TA01928D

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