Issue 3, 2023

Structural engineering of metal–organic layers toward stable Li–CO2 batteries

Abstract

The rational design of metal–organic layers (MOL) with well-exposed catalytic sites and versatile structures holds great promise for boosting CO2 reduction/evolution kinetics in Li–CO2 batteries. In this work, a multifunctional MOL (Mn–TTA MOL) with a rich catalytic surface and flower-like conductive structure was fabricated as an efficient cathodic catalyst for Li–CO2 batteries. Benefiting from the abundant accessible catalytic surface and unique conductive network, the as-developed cells based on the Mn–TTA MOL display high discharge capacity, low polarization, and excellent rate performance. Importantly, superior long-term cycling stability over 300 cycles can be achieved even at a high current density of 1.0 A g−1. The findings provide new insights into catalyst engineering for high-performance Li–CO2 batteries and would advance the development of MOL-based catalysts in various energy storage technologies.

Graphical abstract: Structural engineering of metal–organic layers toward stable Li–CO2 batteries

Supplementary files

Article information

Article type
Paper
Submitted
03 11 2022
Accepted
12 12 2022
First published
13 12 2022

J. Mater. Chem. A, 2023,11, 1180-1187

Structural engineering of metal–organic layers toward stable Li–CO2 batteries

Z. Cheng, Y. Fang, W. Dai, J. Zhang, S. Xiang and Z. Zhang, J. Mater. Chem. A, 2023, 11, 1180 DOI: 10.1039/D2TA08598D

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