Issue 11, 2023

Metal oxide cluster-assisted assembly of anisotropic cellulose nanocrystal aerogels for balanced mechanical and thermal insulation properties

Abstract

Cellulose nanocrystal (CNC) materials grant abundant possibilities for insulation, however, their extensive application is hindered by the intrinsic tradeoff between their thermal insulating performance and mechanical properties. Here, we show that CNC aerogels with balanced thermal and mechanical performance can be fabricated via a 1 nm metal oxide cluster (phosphotungstic acid, PTA)-assisted unidirectional freeze-drying processing. The as-prepared hybrid aerogels with hierarchical porous structures consisting of layer-by-layer CNC nanosheets enable the decoupling of the strengthening of mechanical properties and the enhancement of thermal insulating capabilities. Within layered structures, the surface-doped nanosized PTA clusters with negative charges behave as dynamic physical cross-linking points, and continuous networks of PTA-doped CNC can be formed via multiple supramolecular interactions (e.g., electrostatic attractions and hydrogen bonds). The afforded stable three-dimensional network structures are able to withstand externally applied forces and large deformations, endowing the aerogels with excellent mechanical performance. Moreover, the inter-layer gap is dominated by nanopores, endowing much lower thermal conductivities along the radial direction in comparison to the axial direction. The addition of PTA clusters also contributes to the obvious enhancements of the fire-retardant properties. Our discoveries provide a facile approach for the design and scalable production of CNC-based insulation materials with optimized mechanical properties and additional fire-retardant properties.

Graphical abstract: Metal oxide cluster-assisted assembly of anisotropic cellulose nanocrystal aerogels for balanced mechanical and thermal insulation properties

Supplementary files

Article information

Article type
Paper
Submitted
23 11 2022
Accepted
14 2 2023
First published
14 2 2023

Nanoscale, 2023,15, 5469-5475

Metal oxide cluster-assisted assembly of anisotropic cellulose nanocrystal aerogels for balanced mechanical and thermal insulation properties

H. Wang, B. Xia, R. Song, W. Huang, M. Zhang, C. Liu, Y. Ke, J. Yin, K. Chen and P. Yin, Nanoscale, 2023, 15, 5469 DOI: 10.1039/D2NR06551G

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