Issue 79, 2023

Binding modes of high stoichiometry guest complexes with a Co8L12 cage uncovered by mass spectrometry

Abstract

We demonstrate how different modes of guest binding with a Co8L12 cubic cage can be determined using ESI-MS. High stoichiometry guest binding was observed, with the guests preferentially binding externally, but internal guest inclusion was also seen at higher guest loading.

Graphical abstract: Binding modes of high stoichiometry guest complexes with a Co8L12 cage uncovered by mass spectrometry

Supplementary files

Article information

Article type
Communication
Submitted
31 8 2023
Accepted
12 9 2023
First published
13 9 2023
This article is Open Access
Creative Commons BY-NC license

Chem. Commun., 2023,59, 11811-11814

Binding modes of high stoichiometry guest complexes with a Co8L12 cage uncovered by mass spectrometry

D. L. Stares, C. Mozaceanu, M. D. Ward and C. A. Schalley, Chem. Commun., 2023, 59, 11811 DOI: 10.1039/D3CC04291J

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