Issue 16, 2023

Enhancing the durability of Au clusters in CO2 photoreduction via encapsulation in Cu-based metal–organic frameworks

Abstract

Here, we report the encapsulation of Au25 nanoclusters in a Cu3(BTC)2 metal–organic framework (Au25@Cu-BTC), which can achieve CO2 photoreduction for selective CO production in a gas–solid reaction system at low-concentration CO2 atmospheres (even to 0.1%), with remarkably enhanced durability up to at least 48 h.

Graphical abstract: Enhancing the durability of Au clusters in CO2 photoreduction via encapsulation in Cu-based metal–organic frameworks

Supplementary files

Article information

Article type
Communication
Submitted
09 12 2022
Accepted
30 1 2023
First published
30 1 2023

Chem. Commun., 2023,59, 2299-2302

Enhancing the durability of Au clusters in CO2 photoreduction via encapsulation in Cu-based metal–organic frameworks

J. Zhang, X. Cui, Y. Zhou, T. Kong, Y. Wang, X. Wei and Y. Xiong, Chem. Commun., 2023, 59, 2299 DOI: 10.1039/D2CC06719F

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