Issue 5, 2022

Highly dispersed Ru nanoclusters anchored on B,N co-doped carbon nanotubes for water splitting

Abstract

Boron and nitrogen co-doped carbon nanotubes (CNTs)were developed as a substrate material for the loading of 2–3 nm uniform Ru clusters. Combined with a theoretical and experimental comparison, it was confirmed that B doping as well as its synergistic effect with N-doping in CNTs can effectively reduce the adsorption energy of the H intermediate at Ru site, improving the catalytic activity of the Ru cluster/CNT material for the hydrogen evolution reaction (HER) and the oxygen evolution reaction (OER). Benefiting from the synergistic effect of multi element doping and a porous tubular structure, the as-formed Ru@B,N-CNTs show excellent electrocatalytic activity for both HER and OER in alkaline conditions. An overpotential of 54 mV and 315 mV is needed to achieve a current density of 10 mA cm−2, which exceeds requirements for commercial Pt/C and RuO2. Furthermore, when assembled into an electrolyzer with Ru@B,N-CNTs as both the anode and the cathode, the cell requires a cell voltage of only 1.57 V to drive a current density of 10 mA cm−2 in an alkaline medium and has excellent catalytic stability for over 40 hours.

Graphical abstract: Highly dispersed Ru nanoclusters anchored on B,N co-doped carbon nanotubes for water splitting

Supplementary files

Article information

Article type
Research Article
Submitted
31 12 2021
Accepted
20 1 2022
First published
20 1 2022

Inorg. Chem. Front., 2022,9, 968-976

Highly dispersed Ru nanoclusters anchored on B,N co-doped carbon nanotubes for water splitting

M. Fan, X. Chen, M. Zhang, L. Cui, X. He and X. Zou, Inorg. Chem. Front., 2022, 9, 968 DOI: 10.1039/D1QI01672E

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